trans-Pt(Cl)Ph(P-t-Bu₂Me)2

Base Information

• Chemical Name: trans-Pt(Cl)Ph(P-t-Bu₂Me)2
• CAS No.: 76316-26-2
• Molecular Formula: C₂₄H₄₇ClP₂Pt
• Molecular Weight: 628.118
• Mol file: 76316-26-2.mol

Synonyms:trans-Pt(Cl)Ph(P-t-Bu₂Me)2

Chemical Property of trans-Pt(Cl)Ph(P-t-Bu₂Me)2

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-Pt(Cl)Ph(P-t-Bu₂Me)2

There total 1 articles about trans-Pt(Cl)Ph(P-t-Bu₂Me)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

phenylchloro(1,5-cyclooctadiene)platinum(II) + methyldi-t-butylphosphine (6002-40-0) → trans-Pt(Cl)Ph(P-t-Bu2Me)2 (76316-26-2)

Guidance literature:

In dichloromethane; recrystn. from MeOH/water; elem. anal.;

DOI:10.1016/S0022-328X(00)84529-5

Reference yield: 91.0%

trans-Pt(Cl)Ph(P-t-Bu2Me)2 (76316-26-2) → trans-[PtOH(Ph)(P-t-Bu2Me)2] (76124-94-2)

Guidance literature:

With AgBF₄; KOH; In acetone; byproducts: AgCl; Pt complex was treated with Ag BF4 in acetone; filtration, treating with aq. KOH (N2); stirring; evapn., extn. with hexane, filtration, evapn., recrystn. from n-pentane/isopentane; elem. anal.;

DOI:10.1016/S0022-328X(00)84529-5

Reference yield: 74.0%

trans-Pt(Cl)Ph(P-t-Bu2Me)2 (76316-26-2) → trans-[PtH(Ph)(P-t-Bu2Me)2] (90064-99-6)

Guidance literature:

With methanol; sodium methylate; In methanol; under N2, suspn. of Pt-complex in dry MeOH was treated with 2.8 equiv of NaOCH3, heated under reflux with stirring for 2 h; solvent evapd. under reduced pressure, extd. with n-hexane and water, n-hexane layer sepd., filtered through activated charcoal, dried (Na2SO4), solvent evapd., recrystd. from CH2Cl2-MeOH; elem. anal.;

upstream raw materials:

methyldi-t-butylphosphine

Downstream raw materials:

trans-[PtH(Ph)(P-t-Bu₂Me)2]

trans-[PtOH(Ph)(P-t-Bu₂Me)2]

Refernces