Methyl 2-hydroxy-5-nitrosobenzoate

Base Information

Chemical Name:Methyl 2-hydroxy-5-nitrosobenzoate
CAS No.:22802-57-9
Molecular Formula:C₈H₇NO₄
Molecular Weight:181.148
Hs Code.:
DSSTox Substance ID:DTXSID00570632
Nikkaji Number:J83.221I
Wikidata:Q82458143
Mol file:22802-57-9.mol

Synonyms:Methyl 2-hydroxy-5-nitrosobenzoate;202117-16-6;2-Hydroxy-5-nitrosobenzoic Acid Methyl Ester;starbld0039189;22802-57-9;SCHEMBL25337193;DTXSID00570632;methyl (3Z)-3-hydroxyimino-6-oxocyclohexa-1,4-diene-1-carboxylate;methyl (3Z)-3-(hydroxyimino)-6-oxo-1,4-cyclohexadiene-1-carboxylate

Suppliers and Price of Methyl 2-hydroxy-5-nitrosobenzoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of Methyl 2-hydroxy-5-nitrosobenzoate

Chemical Property:

XLogP3:1.7
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:2
Exact Mass:181.03750770
Heavy Atom Count:13
Complexity:206

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:COC(=O)C1=C(C=CC(=C1)N=O)O

Technology Process of Methyl 2-hydroxy-5-nitrosobenzoate

There total 3 articles about Methyl 2-hydroxy-5-nitrosobenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

: 119-36-8,8024-54-2
methyl salicylate

: 22802-57-9
3-(methoxycarbonyl)-1,4-benzoquinone 1-oxime

Guidance literature:: With i-AmNO₂; potassium carbonate; In N,N-dimethyl-formamide; at 50 ℃; for 41h;
DOI:10.1021/jo951873s

Reference yield:

: 2-methylamino-5-nitroso-benzoic acid methyl ester

: 22802-57-9
3-(methoxycarbonyl)-1,4-benzoquinone 1-oxime

Guidance literature:: With sulfuric acid; bei der Destillation mit Wasserdampf;

Reference yield:

: 85-91-6
Methyl N-methylanthranilate

: 22802-57-9
3-(methoxycarbonyl)-1,4-benzoquinone 1-oxime

Guidance literature:: Multi-step reaction with 2 steps

1: durch Nitrosierung

2: diluted sulfuric acid / bei der Destillation mit Wasserdampf

With sulfuric acid;