S-[(S)-hex-1-yn-3-yl] benzothioate

Base Information

• Chemical Name: S-[(S)-hex-1-yn-3-yl] benzothioate
• CAS No.: 1018479-47-4
• Molecular Formula: C₁₃H₁₆OS
• Molecular Weight: 220.335
• Mol file: 1018479-47-4.mol

Synonyms:S-[(S)-hex-1-yn-3-yl] benzothioate

Chemical Property of S-[(S)-hex-1-yn-3-yl] benzothioate

Chemical Property:

Purity/Quality:

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Technology Process of S-[(S)-hex-1-yn-3-yl] benzothioate

There total 1 articles about S-[(S)-hex-1-yn-3-yl] benzothioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

thiobenzoic acid (98-91-9) + hex-1-yn-3-one (689-00-9) → S-[(S)-hex-1-yn-3-yl] benzothioate (1018479-47-4) + S-[(R)-hex-1-yn-3-yl] benzothioate (1018479-44-1)

Guidance literature:

hex-1-yn-3-one; With dimethylsulfide borane complex; (S)-1-methyl-3,3-diphenyl-hexahydropyrrolo[1,2-c][1,3,2]oxazaborole; In tetrahydrofuran;

thiobenzoic acid; With di-isopropyl azodicarboxylate; triphenylphosphine; In tetrahydrofuran; at 20 ℃; for 15h;

With Lindlar's catalyst; hydrogen; In methanol; at 20 ℃; for 1h; under 760.051 Torr; optical yield given as %ee;

DOI:10.1021/ol8002942

upstream raw materials:

thiobenzoic acid

hex-1-yn-3-one

Refernces