(S)-2-diphenylphosphino-(4-hydroxyphenylthiomethyl)ferrocene

Base Information

• Chemical Name: (S)-2-diphenylphosphino-(4-hydroxyphenylthiomethyl)ferrocene
• CAS No.: 930767-37-6
• Molecular Formula: C₂₉H₂₅FeOPS
• Molecular Weight: 508.404
• Mol file: 930767-37-6.mol

Synonyms:(S)-2-diphenylphosphino-(4-hydroxyphenylthiomethyl)ferrocene

Chemical Property of (S)-2-diphenylphosphino-(4-hydroxyphenylthiomethyl)ferrocene

Chemical Property:

Purity/Quality:

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Technology Process of (S)-2-diphenylphosphino-(4-hydroxyphenylthiomethyl)ferrocene

There total 1 articles about (S)-2-diphenylphosphino-(4-hydroxyphenylthiomethyl)ferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

(S)-2-thiodiphenylphosphino-(4-hydroxyphenylthiomethyl)ferrocene (930767-36-5) → (S)-2-diphenylphosphino-(4-hydroxyphenylthiomethyl)ferrocene (930767-37-6)

Guidance literature:

With tris(dimethylamino)phosphine; In not given; according to Routaboul L., et al., Tetrahedron: Asymmetry, 2005, 16, 2685;

DOI:10.1016/j.jorganchem.2006.10.065

Reference yield: 80.0%

(S)-2-diphenylphosphino-(4-hydroxyphenylthiomethyl)ferrocene (930767-37-6) + N’-benzylidene-N-methylphosphorohydrazidothioic dichloride (245091-45-6) → [((C5H5)Fe((C6H5)2PC5H3CH2SC6H4O))2P(S)N(CH3)NCHC6H5]

Guidance literature:

With Cs₂CO₃; In tetrahydrofuran; (Ar); std. Schlenk technique; Fe complex was added to suspn. of Cs2CO3 in THF; mixt. was stirred at room temp. for 3 h; soln. of P-N compd. in THF was added dropwise; stirred at room temp. overnight; centrifuged; concd. (vac.); pentane added; chromd. (Kieselgel, CH2Cl2); elem. anal.;

DOI:10.1016/j.jorganchem.2006.10.065

upstream raw materials:

(S)-2-thiodiphenylphosphino-(4-hydroxyphenylthiomethyl)ferrocene