NiI(C₆H₄I)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2)

Base Information

Chemical Name:NiI(C₆H₄I)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2)
CAS No.:97921-15-8
Molecular Formula:C₃₂H₅₂I₂NiP₂
Molecular Weight:811.211
Hs Code.:

NiI(C<sub>6</sub>H<sub>4</sub>I)((C<sub>6</sub>H<sub>11</sub>)2PCH<sub>2</sub>CH<sub>2</sub>P(C<sub>6</sub>H<sub>11</sub>)2)

Synonyms:NiI(C₆H₄I)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2)

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Chemical Property of NiI(C₆H₄I)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2)

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Technology Process of NiI(C₆H₄I)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2)

There total 4 articles about NiI(C₆H₄I)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 114907-51-6
[η²-benzyne][1,2-bis(dicyclohexylphosphino)ethane]nickel(0)

: 97921-15-8
NiI(C₆H₄I)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2)

Guidance literature:: With iodine; In tetrahydrofuran; soln. of I2 in THF was added dropwise under N2 to stirred soln. of Ni-complex in THF at -20°C, soln. was allowed to warm to room temp.; mixt. was dild. with hexane and filtered to give crystals of iodo complex; identified by comparison of its (31)P NMR spectrum with that of an authentic sample;

Reference yield: 76.0%

: 91513-98-3
Ni(η(2)-C2H4)(1,2-bis(dicyclohexylphosphino)ethane)

: 615-42-9
1,2-Diiodobenzene

: 97921-15-8
NiI(C₆H₄I)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2)

Guidance literature:: In toluene; o-I2C6H4 and toluene were added under N2 to Ni-complex, mixt. was stirred for 1 h at room temp.; hexane was added, ppt. filtered off, washed with hexane, dissolved in CH2Cl2, rapidly chromd. on acidic alumina, eluate was evapd., residue crystd. on addn. of hexane, recrystd. from CH2Cl2-hexane; elem. anal.;

Reference yield:

: 97921-23-8
NiBr(C₆H₄Br)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2)

: 97921-15-8
NiI(C₆H₄I)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2)

Guidance literature:: Multi-step reaction with 3 steps

1: LiCl; THF / tetrahydrofuran; methanol

2: Na#Hg / tetrahydrofuran

3: iodine / tetrahydrofuran

With LiCl; THF; Na#Hg; iodine; In tetrahydrofuran; methanol;