1-Phenyl-1-(phenylseleno)-2-(p-tolylsulfonyl)-1-hexene Se-oxide

Base Information

• Chemical Name: 1-Phenyl-1-(phenylseleno)-2-(p-tolylsulfonyl)-1-hexene Se-oxide
• CAS No.: 87517-79-1
• Molecular Formula: C₂₅H₂₆O₃SSe
• Molecular Weight: 485.506
• Mol file: 87517-79-1.mol

Synonyms:1-Phenyl-1-(phenylseleno)-2-(p-tolylsulfonyl)-1-hexene Se-oxide

Chemical Property of 1-Phenyl-1-(phenylseleno)-2-(p-tolylsulfonyl)-1-hexene Se-oxide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of 1-Phenyl-1-(phenylseleno)-2-(p-tolylsulfonyl)-1-hexene Se-oxide

There total 3 articles about 1-Phenyl-1-(phenylseleno)-2-(p-tolylsulfonyl)-1-hexene Se-oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

1-Phenyl-1-(phenylseleno)-2-(p-tolylsulfonyl)-1-hexene (87517-78-0) → 1-Phenyl-1-(phenylseleno)-2-(p-tolylsulfonyl)-1-hexene Se-oxide (87517-79-1)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; for 0.5h; Ambient temperature;

DOI:10.1021/jo00172a066

Reference yield:

(hex-1-yn-1-yl)benzene (1129-65-3) → 1-Phenyl-1-(phenylseleno)-2-(p-tolylsulfonyl)-1-hexene Se-oxide (87517-79-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 80 percent / AIBN / benzene / 46 h / Heating

2: 88 percent / MCPBA / tetrahydrofuran / 0.5 h / Ambient temperature

With 2,2'-azobis(isobutyronitrile); 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; benzene;

DOI:10.1021/jo00172a066

Reference yield:

p-tolyl benzeneselenosulfonate (68819-94-3) → 1-Phenyl-1-(phenylseleno)-2-(p-tolylsulfonyl)-1-hexene Se-oxide (87517-79-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 80 percent / AIBN / benzene / 46 h / Heating

2: 88 percent / MCPBA / tetrahydrofuran / 0.5 h / Ambient temperature

With 2,2'-azobis(isobutyronitrile); 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; benzene;

DOI:10.1021/jo00172a066

upstream raw materials:

1-Phenyl-1-(phenylseleno)-2-(p-tolylsulfonyl)-1-hexene

(hex-1-yn-1-yl)benzene

p-tolyl benzeneselenosulfonate

Refernces