2-(1-hexyl-heptyl)-9-[4-(4-hydroxy-phenylamino)-phenyl]-anthra[2,1,9-def;6,5,10-d'e'f']diisoquinoline-1,3,8,10-tetraone

Base Information

• Chemical Name: 2-(1-hexyl-heptyl)-9-[4-(4-hydroxy-phenylamino)-phenyl]-anthra[2,1,9-def;6,5,10-d'e'f']diisoquinoline-1,3,8,10-tetraone
• CAS No.: 832709-09-8
• Molecular Formula: C₄₉H₄₅N₃O₅
• Molecular Weight: 755.913
• Mol file: 832709-09-8.mol

Synonyms:2-(1-hexyl-heptyl)-9-[4-(4-hydroxy-phenylamino)-phenyl]-anthra[2,1,9-def;6,5,10-d'e'f']diisoquinoline-1,3,8,10-tetraone

Chemical Property of 2-(1-hexyl-heptyl)-9-[4-(4-hydroxy-phenylamino)-phenyl]-anthra[2,1,9-def;6,5,10-d'e'f']diisoquinoline-1,3,8,10-tetraone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-(1-hexyl-heptyl)-9-[4-(4-hydroxy-phenylamino)-phenyl]-anthra[2,1,9-def;6,5,10-d'e'f']diisoquinoline-1,3,8,10-tetraone

There total 2 articles about 2-(1-hexyl-heptyl)-9-[4-(4-hydroxy-phenylamino)-phenyl]-anthra[2,1,9-def;6,5,10-d'e'f']diisoquinoline-1,3,8,10-tetraone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.0%

4-hydroxy-4'-aminodiphenylamine (6358-03-8) + N-(1-hexylheptyl)-perylene-3,4,9,10-tetracarboxylic-3,4-carboximide-9,10-anhydride (130296-37-6) → 2-(1-hexyl-heptyl)-9-[4-(4-hydroxy-phenylamino)-phenyl]-anthra[2,1,9-def;6,5,10-d'e'f']diisoquinoline-1,3,8,10-tetraone (832709-09-8)

Guidance literature:

With 1H-imidazole; at 130 ℃; for 5h;

DOI:10.1021/jp045793g

Reference yield:

4-Hydroxy-4'-nitrodiphenylamine (16078-86-7) → 2-(1-hexyl-heptyl)-9-[4-(4-hydroxy-phenylamino)-phenyl]-anthra[2,1,9-def;6,5,10-d'e'f']diisoquinoline-1,3,8,10-tetraone (832709-09-8)

Guidance literature:

Multi-step reaction with 2 steps

1: 76 percent / H₂ / Pd/C / methanol / 18 h / 20 °C / 2068.59 Torr

2: 37 percent / imidazole / 5 h / 130 °C

With 1H-imidazole; hydrogen; palladium on activated charcoal; In methanol;

DOI:10.1021/jp045793g

Reference yield: 38.0%

2-(1-hexyl-heptyl)-9-[4-(4-hydroxy-phenylamino)-phenyl]-anthra[2,1,9-def;6,5,10-d'e'f']diisoquinoline-1,3,8,10-tetraone (832709-09-8) → 2-(1-hexyl-heptyl)-9-[4-(4-oxo-cyclohexa-2,5-dienylideneamino)-phenyl]-anthra[2,1,9-def;6,5,10-d'e'f']diisoquinoline-1,3,8,10-tetraone

Guidance literature:

With sodium hypochlorite; In chloroform; at 20 ℃; for 0.166667h;

DOI:10.1021/jp045793g

upstream raw materials:

4-hydroxy-4'-aminodiphenylamine

N-(1-hexylheptyl)-perylene-3,4,9,10-tetracarboxylic-3,4-carboximide-9,10-anhydride

4-Hydroxy-4'-nitrodiphenylamine