(-)-benzyl N-benzyl,N-<(1R,2S,4S)-6-bromo-7-oxabicyclo<2.2.1>hept-5-en-2-endo-yl>carbamate

Base Information

Chemical Name:(-)-benzyl N-benzyl,N-<(1R,2S,4S)-6-bromo-7-oxabicyclo<2.2.1>hept-5-en-2-endo-yl>carbamate
CAS No.:146352-63-8
Molecular Formula:C₂₁H₂₀BrNO₃
Molecular Weight:414.299
Hs Code.:

Synonyms:(-)-benzyl N-benzyl,N-<(1R,2S,4S)-6-bromo-7-oxabicyclo<2.2.1>hept-5-en-2-endo-yl>carbamate

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Chemical Property of (-)-benzyl N-benzyl,N-<(1R,2S,4S)-6-bromo-7-oxabicyclo<2.2.1>hept-5-en-2-endo-yl>carbamate

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Technology Process of (-)-benzyl N-benzyl,N-<(1R,2S,4S)-6-bromo-7-oxabicyclo<2.2.1>hept-5-en-2-endo-yl>carbamate

There total 10 articles about (-)-benzyl N-benzyl,N-<(1R,2S,4S)-6-bromo-7-oxabicyclo<2.2.1>hept-5-en-2-endo-yl>carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 501-53-1,94274-21-2
benzyl chloroformate

: 146389-05-1
(-)-N-benzyl-N-<(1R,2S,4S)-6-bromo-7-oxabicyclo<2.2.1>hept-5-en-2-endo-yl> amine

: 146352-63-8
(-)-benzyl N-benzyl,N-<(1R,2S,4S)-6-bromo-7-oxabicyclo<2.2.1>hept-5-en-2-endo-yl>carbamate

Guidance literature:: With sodium hydrogencarbonate; In ethanol; water;
DOI:10.1016/S0040-4020(01)88357-5

Reference yield: 80.0%

: 501-53-1,94274-21-2
benzyl chloroformate

: 146352-62-7,146352-78-5,146389-05-1
N-benzyl-N-<(1RS,2RS,4SR)-6-bromo-7-oxabicyclo<2.2.1>hept-5-en-2-exo-yl>amine

: 146352-63-8,146389-06-2,146389-11-9
benzyl N-benzyl,N-<(1RS,2RS,4SR)-6-bromo-7-oxabicyclo<2.2.1>hept-5-en-2-exo-yl>carbamate

Guidance literature:: With sodium hydrogencarbonate; In ethanol; water;
DOI:10.1016/S0040-4020(01)88357-5

Reference yield:

: 146389-03-9
6-bromo-7-oxabicyclo<2.2.1>hept-5-en-2-one

: 146352-63-8,146389-06-2,146389-11-9
(+/-)-benzyl N-benzyl,N-<(1RS,2SR,4SR)-6-bromo-7-oxabicyclo<2.2.1>hept-5-en-2-endo-yl>carbamate

Guidance literature:: Multi-step reaction with 2 steps

1: 14 percent / Na(CN)BH₃, MeSO₃H, 3 Angstroem moelcular sieves / methanol / 14 h

2: NaHCO₃ / ethanol; H₂O

With methanesulfonic acid; 3 A molecular sieve; sodium cyanoborohydride; sodium hydrogencarbonate; In methanol; ethanol; water;
DOI:10.1016/S0040-4020(01)88357-5