C₂₃H₄₂O₄SSi

Base Information

Chemical Name:C₂₃H₄₂O₄SSi
CAS No.:1354656-81-7
Molecular Formula:C₂₃H₄₂O₄SSi
Molecular Weight:442.736
Hs Code.:

C<sub>23</sub>H<sub>42</sub>O<sub>4</sub>SSi

Synonyms:C₂₃H₄₂O₄SSi

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Chemical Property of C₂₃H₄₂O₄SSi

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Technology Process of C₂₃H₄₂O₄SSi

There total 8 articles about C₂₃H₄₂O₄SSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 1354656-80-6
C₁₆H₃₆O₂Si

: 98-59-9
p-toluenesulfonyl chloride

: 1354656-81-7
C₂₃H₄₂O₄SSi

Guidance literature:: With pyridine; dmap; In dichloromethane; at 40 ℃; for 18h; Inert atmosphere;
DOI:10.1021/jo202330b

Reference yield:

: C₂₆H₂₇NO₅

: 1354656-81-7
C₂₃H₄₂O₄SSi

Guidance literature:: Multi-step reaction with 6 steps

1.1: C₃₂H₁₂BF₂₄^(1-)*C₃₉H₅₀IrNOP⁽¹⁺⁾; hydrogen / dichloromethane / 18 h / 20 °C / 60006 - 67506.8 Torr / Inert atmosphere; Autoclave

2.1: sodium hexamethyldisilazane / tetrahydrofuran / 0.75 h / -78 °C / Inert atmosphere

2.2: -78 °C / Inert atmosphere

3.1: sodium tetrahydroborate / tetrahydrofuran; water / 18 h / 0 °C / Inert atmosphere

4.1: 1H-imidazole; dmap / dichloromethane / 1 h / 0 °C / Inert atmosphere

5.1: methanol; potassium carbonate / 18 h / 20 °C / Inert atmosphere

6.1: pyridine; dmap / dichloromethane / 18 h / 40 °C / Inert atmosphere

With pyridine; 1H-imidazole; methanol; dmap; sodium tetrahydroborate; C₃₂H₁₂BF₂₄^(1-)*C₃₉H₅₀IrNOP⁽¹⁺⁾; hydrogen; sodium hexamethyldisilazane; potassium carbonate; In tetrahydrofuran; dichloromethane; water;
DOI:10.1021/jo202330b

Reference yield:

: 1283732-98-8
C₂₆H₂₇NO₅

: 1354656-81-7
C₂₃H₄₂O₄SSi

Guidance literature:: Multi-step reaction with 7 steps

1.1: toluene / 4 h / 180 °C / Inert atmosphere

2.1: C₃₂H₁₂BF₂₄^(1-)*C₃₉H₅₀IrNOP⁽¹⁺⁾; hydrogen / dichloromethane / 18 h / 20 °C / 60006 - 67506.8 Torr / Inert atmosphere; Autoclave

3.1: sodium hexamethyldisilazane / tetrahydrofuran / 0.75 h / -78 °C / Inert atmosphere

3.2: -78 °C / Inert atmosphere

4.1: sodium tetrahydroborate / tetrahydrofuran; water / 18 h / 0 °C / Inert atmosphere

5.1: 1H-imidazole; dmap / dichloromethane / 1 h / 0 °C / Inert atmosphere

6.1: methanol; potassium carbonate / 18 h / 20 °C / Inert atmosphere

7.1: pyridine; dmap / dichloromethane / 18 h / 40 °C / Inert atmosphere

With pyridine; 1H-imidazole; methanol; dmap; sodium tetrahydroborate; C₃₂H₁₂BF₂₄^(1-)*C₃₉H₅₀IrNOP⁽¹⁺⁾; hydrogen; sodium hexamethyldisilazane; potassium carbonate; In tetrahydrofuran; dichloromethane; water; toluene; 1.1: Cope rearrangement;
DOI:10.1021/jo202330b