Fuculose 1-phosphate

Base Information

• Chemical Name: Fuculose 1-phosphate
• CAS No.: 16562-58-6
• Molecular Formula: C₆H₁₃O₈P
• Molecular Weight: 244.138
• DSSTox Substance ID: DTXSID301027442
• Wikidata: Q27103634
• Metabolomics Workbench ID: 37693
• Mol file: 16562-58-6.mol

Synonyms:fuculose 1-phosphate

Chemical Property of Fuculose 1-phosphate

Chemical Property:

• Vapor Pressure: 5.83E-13mmHg at 25°C
• Boiling Point: 519.4°Cat760mmHg
• Flash Point: 267.9°C
• PSA: 146.49000
• Density: 1.75g/cm³
• LogP: -2.07680
• XLogP3: -3.2
• Hydrogen Bond Donor Count: 5
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 2
• Exact Mass: 244.03480437
• Heavy Atom Count: 15
• Complexity: 264

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1C(C(C(C(O1)OP(=O)(O)O)O)O)O
• Isomeric SMILES: C[C@H]1[C@H]([C@H]([C@@H](C(O1)OP(=O)(O)O)O)O)O

Technology Process of Fuculose 1-phosphate

There total 3 articles about Fuculose 1-phosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,3,4-tri-O-acetyl-α-L-fucopyranosyl bromide (16741-27-8) → L-fucose-1-phosphate (16562-58-6,28553-11-9)

Guidance literature:

Multi-step reaction with 2 steps

1: dimethylformamide / 0.17 h / 23 °C

In N,N-dimethyl-formamide;

DOI:10.1139/v90-165

Reference yield:

dibenzylphosphoryl 2,3,4-tri-O-acetyl-L-fucoside (374726-38-2) → L-fucose-1-phosphate (16562-58-6,28553-11-9)

Guidance literature:

Yield given. Multistep reaction;

DOI:10.1139/v90-165

Reference yield:

→ β-L-Rhamnopyranosylphosphat (16562-58-6,16562-59-7,23880-96-8,24809-76-5,40591-48-8,40591-49-9,40591-52-4,62357-79-3,69980-07-0,81276-27-9,120522-69-2,28553-11-9)

Guidance literature:

Aus Pyranosylphosphat III, Pb(OAc)4, LiOH;

DOI:10.1007/BF00923209

upstream raw materials:

dibenzylphosphoryl 2,3,4-tri-O-acetyl-L-fucoside

2,3,4-tri-O-acetyl-α-L-fucopyranosyl bromide

Downstream raw materials:

guanosine-5'-diphospho-β-L-fucose