Technology Process of 1,4-bis(decyloxy)-2-ethynyl-5-triisopropylsilylethynylbenzene
There total 6 articles about 1,4-bis(decyloxy)-2-ethynyl-5-triisopropylsilylethynylbenzene which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
potassium carbonate;
In
tetrahydrofuran; methanol;
at 20 ℃;
for 3h;
DOI:10.1021/ol049447t
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 80 percent / KOH / ethanol / Heating
2: 83 percent / I2; Hg(OAc)2 / CH2Cl2 / 20 °C
3: 58 percent / CuI; TEA / [PdCl2(PPh3)2] / 20 °C
4: 96 percent / CuI; TEA / PdCl2(PPh3)2 / 20 °C
5: 86 percent / K2CO3 / tetrahydrofuran; methanol / 3 h / 20 °C
With
potassium hydroxide; copper(l) iodide; TEA; mercury(II) diacetate; iodine; potassium carbonate;
bis-triphenylphosphine-palladium(II) chloride;
In
tetrahydrofuran; methanol; ethanol; dichloromethane;
3: Sonogashira reaction / 4: Sonogashira reaction;
DOI:10.1002/chem.200401198
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 83 percent / I2; Hg(OAc)2 / CH2Cl2 / 20 °C
2: 58 percent / CuI; TEA / [PdCl2(PPh3)2] / 20 °C
3: 96 percent / CuI; TEA / PdCl2(PPh3)2 / 20 °C
4: 86 percent / K2CO3 / tetrahydrofuran; methanol / 3 h / 20 °C
With
copper(l) iodide; TEA; mercury(II) diacetate; iodine; potassium carbonate;
bis-triphenylphosphine-palladium(II) chloride;
In
tetrahydrofuran; methanol; dichloromethane;
2: Sonogashira reaction / 3: Sonogashira reaction;
DOI:10.1002/chem.200401198
