1,4-bis(dimethylstibanyl)benzene

Base Information

Chemical Name:1,4-bis(dimethylstibanyl)benzene
CAS No.:691363-94-7
Molecular Formula:C₁₀H₁₆Sb₂
Molecular Weight:379.737
Hs Code.:

Synonyms:1,4-bis(dimethylstibanyl)benzene

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Chemical Property of 1,4-bis(dimethylstibanyl)benzene

Chemical Property:

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Technology Process of 1,4-bis(dimethylstibanyl)benzene

There total 1 articles about 1,4-bis(dimethylstibanyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 106-37-6
1.4-dibromobenzene

: 120-12-7
anthracene

: 18380-68-2
dimethylchlorostibine

: 691363-94-7
1,4-bis(dimethylstibanyl)benzene

Guidance literature:: With Mg; 1,2-dibromethane; In toluene; (N2); mixing of Mg powder and anthracene activated with 1,2-dibromoethane in THF; addn. of more THF; addn. dropwise of 1,4-dibromobenzene; reflux for 3 h; cooling, addn. of soln. of Me2SbCl in toluene; stirring overnight; addn. of aq. NH4Cl; sepn. of org. layer; ext. of aq. layer with Et2O; drying of combined organics over anhyd. MgSO4; removal of solvent in vac.,addn. of Et2O; filtration, removal of solid; removal of solvent in vac.;
DOI:10.1039/b312083j

Reference yield: 51.0%

: 15321-51-4
diiron nonacarbonyl

: 691363-94-7
1,4-bis(dimethylstibanyl)benzene

: [Fe(CO)4(η1-1,4-C6H4(SbMe2)2)]

Guidance literature:: In tetrahydrofuran; (N2); addn. of soln. of 1,4-C6H4(SbMe2)2 in dry THF to soln. of Fe2(CO)9(2 equiv.) in dry THF; stirring at room temp. for 15 h; removal of solvent in vac., addn. of CH2Cl2; filtration, removal of solvent in vac., trituration with ice-cold pentane;
DOI:10.1039/b312083j

Reference yield:

: 691363-94-7
1,4-bis(dimethylstibanyl)benzene

: 13463-39-3,71564-36-8
tetracarbonyl nickel

: 691364-09-7
[Ni(CO)3(η1-1,4-C6H4(SbMe2)2)]

: 691364-10-0
[(Ni(CO)3)2(1,4-C₆H₄(SbMe₂)2)]

: 691364-11-1
[Ni(CO)2(1,4-C₆H₄(SbMe₂)2)]2

Guidance literature:: In dichloromethane; (N2); injecting of Ni(CO)4 into soln. of 1,4-C6H4(SbMe2)2 in CH2Cl2; stirring at room temp. for 3 h; removal of solvent in vac.; as inseparable mixt.;
DOI:10.1039/b312083j