(2S,3S,4R,5S,6R,7R,10S,12S,13S,14R,15S,16S)-3,5,10,13,15,17-hexakis(tert-butyldimethylsilyloxy)-7-hydroxy-1-(4-methoxybenzyloxy)-2,4,6,12,14,16-hexamethylheptadecan-9-one

Base Information

Chemical Name:(2S,3S,4R,5S,6R,7R,10S,12S,13S,14R,15S,16S)-3,5,10,13,15,17-hexakis(tert-butyldimethylsilyloxy)-7-hydroxy-1-(4-methoxybenzyloxy)-2,4,6,12,14,16-hexamethylheptadecan-9-one
CAS No.:1238365-02-0
Molecular Formula:C₆₇H₁₃₈O₁₀Si₆
Molecular Weight:1272.34
Hs Code.:

(2S,3S,4R,5S,6R,7R,10S,12S,13S,14R,15S,16S)-3,5,10,13,15,17-hexakis(tert-butyldimethylsilyloxy)-7-hydroxy-1-(4-methoxybenzyloxy)-2,4,6,12,14,16-hexamethylheptadecan-9-one

Synonyms:(2S,3S,4R,5S,6R,7R,10S,12S,13S,14R,15S,16S)-3,5,10,13,15,17-hexakis(tert-butyldimethylsilyloxy)-7-hydroxy-1-(4-methoxybenzyloxy)-2,4,6,12,14,16-hexamethylheptadecan-9-one

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Chemical Property of (2S,3S,4R,5S,6R,7R,10S,12S,13S,14R,15S,16S)-3,5,10,13,15,17-hexakis(tert-butyldimethylsilyloxy)-7-hydroxy-1-(4-methoxybenzyloxy)-2,4,6,12,14,16-hexamethylheptadecan-9-one

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Technology Process of (2S,3S,4R,5S,6R,7R,10S,12S,13S,14R,15S,16S)-3,5,10,13,15,17-hexakis(tert-butyldimethylsilyloxy)-7-hydroxy-1-(4-methoxybenzyloxy)-2,4,6,12,14,16-hexamethylheptadecan-9-one

There total 1 articles about (2S,3S,4R,5S,6R,7R,10S,12S,13S,14R,15S,16S)-3,5,10,13,15,17-hexakis(tert-butyldimethylsilyloxy)-7-hydroxy-1-(4-methoxybenzyloxy)-2,4,6,12,14,16-hexamethylheptadecan-9-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

: 1238365-00-8
C₃₀H₅₆O₅Si₂

: 1238364-80-1
(3S,5S,6S,7R,8S,9S)-3,6,8,10-tetrakis(tert-butyldimethylsilyloxy)-5,7,9-trimethyl-dec-1-yne

: 1238365-02-0
(2S,3S,4R,5S,6R,7R,10S,12S,13S,14R,15S,16S)-3,5,10,13,15,17-hexakis(tert-butyldimethylsilyloxy)-7-hydroxy-1-(4-methoxybenzyloxy)-2,4,6,12,14,16-hexamethylheptadecan-9-one

: 1238365-12-2
C₆₇H₁₃₈O₁₀Si₆

Guidance literature:: (3S,5S,6S,7R,8S,9S)-3,6,8,10-tetrakis(tert-butyldimethylsilyloxy)-5,7,9-trimethyl-dec-1-yne; With lithium diisopropyl amide; In tetrahydrofuran; at -78 ℃; for 2h;

C₃₀H₅₆O₅Si₂; In tetrahydrofuran; at -78 ℃; for 2h; optical yield given as %de; diastereoselective reaction;
DOI:10.1021/jo100871m

Reference yield: 81.0%

: 1238365-02-0
(2S,3S,4R,5S,6R,7R,10S,12S,13S,14R,15S,16S)-3,5,10,13,15,17-hexakis(tert-butyldimethylsilyloxy)-7-hydroxy-1-(4-methoxybenzyloxy)-2,4,6,12,14,16-hexamethylheptadecan-9-one

: 420-37-1
trimethoxonium tetrafluoroborate

: 1238365-03-1
(2S,3S,4R,5S,6R,7R,10S,12S,13S,14R,15S,16S)-3,5,10,13,15,17-hexakis(tert-butyldimethylsilyloxy)-7-methoxy-1-(4-methoxybenzyloxy)-2,4,6,12,14,16-hexamethylheptadecan-9-one

Guidance literature:: With N,N,N',N'-tetramethyl-1,8-diaminonaphthalene; In dichloromethane; at 0 - 20 ℃; Molecular sieve;
DOI:10.1021/jo100871m