Bis-{2-[(S)-(2-methoxy-phenyl)-phenyl-phosphinoyl]-ethyl}-phenyl-phosphane

Base Information

Chemical Name:Bis-{2-[(S)-(2-methoxy-phenyl)-phenyl-phosphinoyl]-ethyl}-phenyl-phosphane
CAS No.:108058-68-0
Molecular Formula:C₃₆H₃₇O₄P₃
Molecular Weight:626.609
Hs Code.:

Synonyms:Bis-{2-[(S)-(2-methoxy-phenyl)-phenyl-phosphinoyl]-ethyl}-phenyl-phosphane

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Chemical Property of Bis-{2-[(S)-(2-methoxy-phenyl)-phenyl-phosphinoyl]-ethyl}-phenyl-phosphane

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Technology Process of Bis-{2-[(S)-(2-methoxy-phenyl)-phenyl-phosphinoyl]-ethyl}-phenyl-phosphane

There total 4 articles about Bis-{2-[(S)-(2-methoxy-phenyl)-phenyl-phosphinoyl]-ethyl}-phenyl-phosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 108058-67-9
(-)-(S_P)-(2-methoxyphenyl)phenylvinylphosphine oxide

: 638-21-1
phenylphosphane

: 108058-68-0
Bis-{2-[(S)-(2-methoxy-phenyl)-phenyl-phosphinoyl]-ethyl}-phenyl-phosphane

Guidance literature:: With potassium hydroxide; In acetonitrile; for 5h; Ambient temperature;
DOI:10.1021/jo00387a010

Reference yield:

: 20663-35-8
(S_p)-(2-methoxyphenyl)methylphenylphosphine oxide

: 108058-68-0
Bis-{2-[(S)-(2-methoxy-phenyl)-phenyl-phosphinoyl]-ethyl}-phenyl-phosphane

Guidance literature:: Multi-step reaction with 3 steps

1: 71 percent / LDA, CuCl₂ / tetrahydrofuran; hexane / 1.) -78 deg C, 1 h, 2.) RT, 0.5 h

2: 82 percent / xylene / 1 h / Heating

3: 79 percent / 10 N aq. KOH / acetonitrile / 5 h / Ambient temperature

With potassium hydroxide; copper dichloride; lithium diisopropyl amide; In tetrahydrofuran; hexane; acetonitrile; xylene;
DOI:10.1021/jo00387a010

Reference yield:

: 108058-66-8,108058-69-1
(PS,SRS)-S-<2-<(0-methoxyphenyl)phenylphosphinyl>ethyl>-N-methyl-S-phenylsulfoximine

: 108058-68-0
Bis-{2-[(S)-(2-methoxy-phenyl)-phenyl-phosphinoyl]-ethyl}-phenyl-phosphane

Guidance literature:: Multi-step reaction with 2 steps

1: 82 percent / xylene / 1 h / Heating

2: 79 percent / 10 N aq. KOH / acetonitrile / 5 h / Ambient temperature

With potassium hydroxide; In acetonitrile; xylene;
DOI:10.1021/jo00387a010