methyl (2-O-acetyl-3,4-di-O-benzyl-α-D-glucopyranosyl)uronate trichloroacetimidate

Base Information

Chemical Name:methyl (2-O-acetyl-3,4-di-O-benzyl-α-D-glucopyranosyl)uronate trichloroacetimidate
CAS No.:666238-37-5
Molecular Formula:C₂₅H₂₆Cl₃NO₈
Molecular Weight:574.842
Hs Code.:

Synonyms:methyl (2-O-acetyl-3,4-di-O-benzyl-α-D-glucopyranosyl)uronate trichloroacetimidate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl (2-O-acetyl-3,4-di-O-benzyl-α-D-glucopyranosyl)uronate trichloroacetimidate

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Technology Process of methyl (2-O-acetyl-3,4-di-O-benzyl-α-D-glucopyranosyl)uronate trichloroacetimidate

There total 1 articles about methyl (2-O-acetyl-3,4-di-O-benzyl-α-D-glucopyranosyl)uronate trichloroacetimidate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 545-06-2
trichloroacetonitrile

: methyl-2-O-acetyl-3,4-O-benzyl-D-glucupyranosyluronate

: 666238-37-5
methyl (2-O-acetyl-3,4-di-O-benzyl-α-D-glucopyranosyl)uronate trichloroacetimidate

Guidance literature:: With sodium hydride; In dichloromethane; at 20 ℃; for 3h;
DOI:10.1081/CAR-120026603

Reference yield: 71.0%

: 52813-63-5
(5R)-2,3,4,5-tetrahydro-5-hydroxymethyl-2-furanone

: 666238-37-5
methyl (2-O-acetyl-3,4-di-O-benzyl-α-D-glucopyranosyl)uronate trichloroacetimidate

: 666238-73-9
methyl [(2-R)-2,3,4,5-tetrahydro-5-oxo-2-furylmethyl 2-O-acetyl-3,4-di-O-benzyl-β-D-glucopyranosid]uronate

Guidance literature:: With boron trifluoride diethyl etherate; In dichloromethane; at -20 ℃; for 2h;
DOI:10.1081/CAR-120026603

Reference yield:

: 666238-37-5
methyl (2-O-acetyl-3,4-di-O-benzyl-α-D-glucopyranosyl)uronate trichloroacetimidate

: 666238-86-4
(2-R)-2,3,4,5-tetrahydro-5-oxo-2-furylmethyl 3,4-di-O-benzyl-β-D-glucopyranosiduronic acid

Guidance literature:: Multi-step reaction with 3 steps

1: 71 percent / boron trifluoride etherate / CH₂Cl₂ / 2 h / -20 °C

2: 75 percent / sodium methoxide / methanol; CH₂Cl₂ / 4 h / 20 °C

3: 88 percent / aq. LiOH / acetone / 3 h / 20 °C

With lithium hydroxide; boron trifluoride diethyl etherate; sodium methylate; In methanol; dichloromethane; acetone;
DOI:10.1081/CAR-120026603