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hexafluorophosphate [5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrinato]aurate(III)

Base Information
  • Chemical Name:hexafluorophosphate [5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrinato]aurate(III)
  • CAS No.:136316-46-6
  • Molecular Formula:C76H92AuN4*F6P
  • Molecular Weight:1403.52
  • Hs Code.:
hexafluorophosphate [5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrinato]aurate(III)

Synonyms:hexafluorophosphate [5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrinato]aurate(III)

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Chemical Property of hexafluorophosphate [5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrinato]aurate(III)
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Technology Process of hexafluorophosphate [5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrinato]aurate(III)

There total 1 articles about hexafluorophosphate [5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrinato]aurate(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:
Guidance literature:
With sodium acetate; In dichloromethane; acetic acid; soln. porphyrin, K(AuCl4), and AcONa in CH2Cl-AcOH heated at reflux for 24 h, diluted with CHCl3, washed with water, aq. Na2CO3, and water, dried over Na2SO4, filtered, evapd., dissolved in CH2Cl2, aq. soln. KPF6 wasadded and stirred for 24 h; react. mixt. was diluted with CH2Cl2, washed with water, and dried over Na2SO4, soln. was evapd. in vacuo, residue was chromed. on silica (CHCl3-MeOH 50:1); elem. anal.;
DOI:10.1021/ic035070w
Guidance literature:
With naphtalene radical anion; In dimethyl sulfoxide; not isolated; confirmed by ESR;
DOI:10.1039/b109795d
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