methyl 4-O-benzyl-6-bromo-6-deoxy-4-O-(methoxyethoxymethyl)-2,3-di-O-methyl-α-D-glucopyranoside

Base Information

Chemical Name:methyl 4-O-benzyl-6-bromo-6-deoxy-4-O-(methoxyethoxymethyl)-2,3-di-O-methyl-α-D-glucopyranoside
CAS No.:108223-99-0
Molecular Formula:C₁₆H₂₃BrO₅
Molecular Weight:375.26
Hs Code.:

Synonyms:methyl 4-O-benzyl-6-bromo-6-deoxy-4-O-(methoxyethoxymethyl)-2,3-di-O-methyl-α-D-glucopyranoside

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Chemical Property of methyl 4-O-benzyl-6-bromo-6-deoxy-4-O-(methoxyethoxymethyl)-2,3-di-O-methyl-α-D-glucopyranoside

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Technology Process of methyl 4-O-benzyl-6-bromo-6-deoxy-4-O-(methoxyethoxymethyl)-2,3-di-O-methyl-α-D-glucopyranoside

There total 2 articles about methyl 4-O-benzyl-6-bromo-6-deoxy-4-O-(methoxyethoxymethyl)-2,3-di-O-methyl-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 3013-58-9,3051-89-6,4261-46-5,6748-99-8,13035-20-6,13502-46-0,22893-88-5,35311-32-1,53767-28-5,56586-53-9,56586-54-0,69744-11-2,94480-09-8,120200-48-8,120200-49-9,120200-50-2,120200-52-4
methyl 4,6-O-benzylidene-2,3-di-O-methyl-α-D-glucopyranoside

: 108223-99-0
methyl 4-O-benzyl-6-bromo-6-deoxy-4-O-(methoxyethoxymethyl)-2,3-di-O-methyl-α-D-glucopyranoside

Guidance literature:: With N-Bromosuccinimide; barium carbonate; In tetrachloromethane; Heating;

Reference yield:

: 56543-17-0
methyl 4-O-benzoyl-6-bromo-6-deoxy-2,3-di-O-methyl-α-D-glucopyranoside

: 108223-99-0
methyl 4-O-benzyl-6-bromo-6-deoxy-4-O-(methoxyethoxymethyl)-2,3-di-O-methyl-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 92 percent / NaOMe, / methanol

2: 55 percent / NaH, / tetrahydrofuran / Heating

With sodium methylate; sodium hydride; In tetrahydrofuran; methanol;
DOI:10.1016/S0008-6215(00)90149-6

Reference yield:

: 108223-99-0
methyl 4-O-benzyl-6-bromo-6-deoxy-4-O-(methoxyethoxymethyl)-2,3-di-O-methyl-α-D-glucopyranoside

: 2-((2R,3R,4S,5R,6S)-3-Benzyloxy-4,5,6-trimethoxy-tetrahydro-pyran-2-yl)-ethylamine

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) tetrabutylammonium tetrafluoroborate, / 1.) DMF, 2 h, 2.) DMF, 7 d,

2: LiAlH₄, / diethyl ether / 0.25 h / 0 °C

With lithium aluminium tetrahydride; tetrabutylammonium tetrafluoroborate; In diethyl ether;
DOI:10.1016/S0008-6215(00)90149-6