Phosphoric acid 3-(tert-butyl-dimethyl-silanyloxy)-2,6,6-trimethyl-cyclohexa-1,3-dienyl ester diethyl ester

Base Information

• Chemical Name: Phosphoric acid 3-(tert-butyl-dimethyl-silanyloxy)-2,6,6-trimethyl-cyclohexa-1,3-dienyl ester diethyl ester
• CAS No.: 169889-13-8
• Molecular Formula: C₁₉H₃₇O₅PSi
• Molecular Weight: 404.559
• Mol file: 169889-13-8.mol

Synonyms:Phosphoric acid 3-(tert-butyl-dimethyl-silanyloxy)-2,6,6-trimethyl-cyclohexa-1,3-dienyl ester diethyl ester

Chemical Property of Phosphoric acid 3-(tert-butyl-dimethyl-silanyloxy)-2,6,6-trimethyl-cyclohexa-1,3-dienyl ester diethyl ester

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of Phosphoric acid 3-(tert-butyl-dimethyl-silanyloxy)-2,6,6-trimethyl-cyclohexa-1,3-dienyl ester diethyl ester

There total 1 articles about Phosphoric acid 3-(tert-butyl-dimethyl-silanyloxy)-2,6,6-trimethyl-cyclohexa-1,3-dienyl ester diethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

diethyl chlorophosphate (814-49-3) + 3-(tert-Butyl-dimethyl-silanyloxy)-2,6,6-trimethyl-cyclohex-2-enone → Phosphoric acid 3-(tert-butyl-dimethyl-silanyloxy)-2,6,6-trimethyl-cyclohexa-1,3-dienyl ester diethyl ester (169889-13-8)

Guidance literature:

With lithium hexamethyldisilazane; In tetrahydrofuran;

DOI:10.1016/0040-4039(95)00871-9

Reference yield: 90.0%

Phosphoric acid 3-(tert-butyl-dimethyl-silanyloxy)-2,6,6-trimethyl-cyclohexa-1,3-dienyl ester diethyl ester (169889-13-8) → Phosphoric acid diethyl ester 2,6,6-trimethyl-3-oxo-cyclohex-1-enyl ester

Guidance literature:

With hydrogenchloride; In tetrahydrofuran;

DOI:10.1016/0040-4039(95)00871-9

Reference yield: 77.0%

Phosphoric acid 3-(tert-butyl-dimethyl-silanyloxy)-2,6,6-trimethyl-cyclohexa-1,3-dienyl ester diethyl ester (169889-13-8) → 3-iodo-2,4,4-trimethyl-2-cyclohexen-1-one

Guidance literature:

With trimethylsilyl iodide; In dichloromethane;

DOI:10.1016/0040-4039(95)00871-9

upstream raw materials:

diethyl chlorophosphate