bis(2-hexa-1,5-dienyl)dimethylstannane

Base Information

• Chemical Name: bis(2-hexa-1,5-dienyl)dimethylstannane
• CAS No.: 134940-88-8
• Molecular Formula: C₁₄H₂₄Sn
• Molecular Weight: 311.055
• Mol file: 134940-88-8.mol

Synonyms:bis(2-hexa-1,5-dienyl)dimethylstannane

Chemical Property of bis(2-hexa-1,5-dienyl)dimethylstannane

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of bis(2-hexa-1,5-dienyl)dimethylstannane

There total 1 articles about bis(2-hexa-1,5-dienyl)dimethylstannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

2,5-bis(trimethylstannyl)-1,5-hexadiene (90886-28-5) + methyllithium (917-54-4) → 2-(trimethylstannyl)-1,5-hexadiene (125405-30-3) + bis(2-hexa-1,5-dienyl)dimethylstannane (134940-88-8) + 1-(2-hexa-1,5-dienyl)-1-methyl-2,5-bis(methylene)stannolane (134967-25-2) + tetramethylstannane (594-27-4)

Guidance literature:

In tetrahydrofuran; under argon, compounds were added at -78°C, stirring at this temp. for 5 min, mixt. was warmed to 25°C for 10 min and cooled to -78°C, mixt was transfered to a soln. of water in THF; solvent was removed under vacuum, resulting oil was purified by glpc, elem. anal., mass spectrum;

DOI:10.1021/om00053a054

upstream raw materials:

2,5-bis(trimethylstannyl)-1,5-hexadiene

methyllithium