C₅₅H₈₄O₁₄Si₂

Base Information

Chemical Name:C₅₅H₈₄O₁₄Si₂
CAS No.:256342-09-3
Molecular Formula:C₅₅H₈₄O₁₄Si₂
Molecular Weight:1025.43
Hs Code.:

C<sub>55</sub>H<sub>84</sub>O<sub>14</sub>Si<sub>2</sub>

Synonyms:C₅₅H₈₄O₁₄Si₂

Suppliers and Price of C₅₅H₈₄O₁₄Si₂

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of C₅₅H₈₄O₁₄Si₂

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of C₅₅H₈₄O₁₄Si₂

There total 38 articles about C₅₅H₈₄O₁₄Si₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 306726-10-3
(1R,2S,3S)-2,3-Bis-allyloxy-4-(tert-butyl-diphenyl-silanyloxy)-1-thiazol-2-yl-butan-1-ol

: 256342-09-3
C₅₅H₈₄O₁₄Si₂

Guidance literature:: Multi-step reaction with 20 steps

1.1: 98 percent / Et₃N; DMAP / CH₂Cl₂ / 2 h / 0 - 25 °C

2.1: molecular sieves 4 Angstroem / acetonitrile / 0.25 h / 25 °C

3.1: NaBH₄ / methanol / 0.5 h / 0 °C

3.2: H₂O; CuCl₂; CuO / acetonitrile / 2 h / 25 °C

4.1: 10.97 g / TBAF; AcOH / 2 h / 25 °C

5.1: 85 percent / DBU / CH₂Cl₂ / 0.5 h / 0 °C

6.1: nBu₂SnO / methanol / 3 h / Heating

6.2: TMSOTf / CH₂Cl₂ / 12 h / 0 - 25 °C

6.3: 10.82 g / PPTS; MeOH / 1 h / 25 °C

7.1: 87 percent / NaH / dimethylformamide / 1 h / 0 - 25 °C

8.1: 95 percent / NaOH; MeOH / diethyl ether / 1 h / 25 °C

9.1: NaH / dimethylformamide / 0.08 h / 0 °C

9.2: 90 percent / nBu₄NI / dimethylformamide / 4 h / 0 - 25 °C

10.1: 91 percent / DDQ; H₂O / CH₂Cl₂ / 1 h / 0 - 25 °C

11.1: 97 percent / 2,6-lutidine / CH₂Cl₂ / 1 h / 0 - 25 °C

12.1: DABCO / [(Ph₃P)3RhCl] / aq. ethanol / 2 h / Heating

13.1: 9.27 g / NMO; OsO₄; H₂O / acetone / 8 h / 25 °C

14.1: nBu₂SnO / toluene / 3 h / Heating

14.2: toluene / 1 h / 0 - 25 °C

15.1: 96 percent / Et₃N; DMAP / CH₂Cl₂ / 2 h / 0 - 25 °C

16.1: 96 percent / Et₃N; MeOH / CH₂Cl₂ / 6 h / 40 °C

17.1: 92 percent / SnCl₂; molecular sieves 4 Angstroem / diethyl ether / 3 h / 0 - 25 °C

18.1: 98 percent / K₂CO₃; MeOH / diethyl ether / 12 h / 25 °C

19.1: aq. NaIO₄; NaHCO₃ / methanol; CH₂Cl₂ / 2 h / 25 °C

20.1: 430 mg / iPr₂NH; vinyl acetate / toluene / 12 h / 140 °C

With 1,4-diaza-bicyclo[2.2.2]octane; 2,6-dimethylpyridine; methanol; dmap; sodium hydroxide; sodium tetrahydroborate; sodium periodate; osmium(VIII) oxide; vinyl acetate; N-methyl-2-indolinone; 4 A molecular sieve; tetrabutyl ammonium fluoride; water; sodium hydride; di(n-butyl)tin oxide; sodium hydrogencarbonate; potassium carbonate; acetic acid; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; diisopropylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; tin(ll) chloride; Wilkinson's catalyst; In methanol; diethyl ether; ethanol; dichloromethane; N,N-dimethyl-formamide; acetone; toluene; acetonitrile; 1.1: Esterification / 2.1: Methylation / 3.1: Reduction / 3.2: Ring cleavage / 4.1: Cyclization / 5.1: Addition / 6.1: Cyclization / 6.2: Ring cleavage / 6.3: Methanolysis / 7.1: Methylation / 8.1: Debenzoylation / 9.1: Metallation / 9.2: Etherification / 10.1: Oxidation / 11.1: Etherification / 12.1: Isomerization / 13.1: Oxidation / 14.1: Cyclization / 14.2: Ring cleavage / 15.1: Esterification / 16.1: Deacylation / 17.1: Glycosidation / 18.1: Debenzoylation / 19.1: Oxidation / 20.1: Cyclizati;
DOI:10.1002/1521-3765(20000901)6:17<3116::AID-CHEM3116>3.0.CO;2-8

Reference yield:

: 306726-12-5
Benzoic acid (1R,2R,3S)-2,3-bis-allyloxy-4-(tert-butyl-diphenyl-silanyloxy)-1-thiazol-2-yl-butyl ester

: 256342-09-3
C₅₅H₈₄O₁₄Si₂

Guidance literature:: Multi-step reaction with 19 steps

1.1: molecular sieves 4 Angstroem / acetonitrile / 0.25 h / 25 °C

2.1: NaBH₄ / methanol / 0.5 h / 0 °C

2.2: H₂O; CuCl₂; CuO / acetonitrile / 2 h / 25 °C

3.1: 10.97 g / TBAF; AcOH / 2 h / 25 °C

4.1: 85 percent / DBU / CH₂Cl₂ / 0.5 h / 0 °C

5.1: nBu₂SnO / methanol / 3 h / Heating

5.2: TMSOTf / CH₂Cl₂ / 12 h / 0 - 25 °C

5.3: 10.82 g / PPTS; MeOH / 1 h / 25 °C

6.1: 87 percent / NaH / dimethylformamide / 1 h / 0 - 25 °C

7.1: 95 percent / NaOH; MeOH / diethyl ether / 1 h / 25 °C

8.1: NaH / dimethylformamide / 0.08 h / 0 °C

8.2: 90 percent / nBu₄NI / dimethylformamide / 4 h / 0 - 25 °C

9.1: 91 percent / DDQ; H₂O / CH₂Cl₂ / 1 h / 0 - 25 °C

10.1: 97 percent / 2,6-lutidine / CH₂Cl₂ / 1 h / 0 - 25 °C

11.1: DABCO / [(Ph₃P)3RhCl] / aq. ethanol / 2 h / Heating

12.1: 9.27 g / NMO; OsO₄; H₂O / acetone / 8 h / 25 °C

13.1: nBu₂SnO / toluene / 3 h / Heating

13.2: toluene / 1 h / 0 - 25 °C

14.1: 96 percent / Et₃N; DMAP / CH₂Cl₂ / 2 h / 0 - 25 °C

15.1: 96 percent / Et₃N; MeOH / CH₂Cl₂ / 6 h / 40 °C

16.1: 92 percent / SnCl₂; molecular sieves 4 Angstroem / diethyl ether / 3 h / 0 - 25 °C

17.1: 98 percent / K₂CO₃; MeOH / diethyl ether / 12 h / 25 °C

18.1: aq. NaIO₄; NaHCO₃ / methanol; CH₂Cl₂ / 2 h / 25 °C

19.1: 430 mg / iPr₂NH; vinyl acetate / toluene / 12 h / 140 °C

With 1,4-diaza-bicyclo[2.2.2]octane; 2,6-dimethylpyridine; methanol; dmap; sodium hydroxide; sodium tetrahydroborate; sodium periodate; osmium(VIII) oxide; vinyl acetate; N-methyl-2-indolinone; 4 A molecular sieve; tetrabutyl ammonium fluoride; water; sodium hydride; di(n-butyl)tin oxide; sodium hydrogencarbonate; potassium carbonate; acetic acid; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; diisopropylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; tin(ll) chloride; Wilkinson's catalyst; In methanol; diethyl ether; ethanol; dichloromethane; N,N-dimethyl-formamide; acetone; toluene; acetonitrile; 1.1: Methylation / 2.1: Reduction / 2.2: Ring cleavage / 3.1: Cyclization / 4.1: Addition / 5.1: Cyclization / 5.2: Ring cleavage / 5.3: Methanolysis / 6.1: Methylation / 7.1: Debenzoylation / 8.1: Metallation / 8.2: Etherification / 9.1: Oxidation / 10.1: Etherification / 11.1: Isomerization / 12.1: Oxidation / 13.1: Cyclization / 13.2: Ring cleavage / 14.1: Esterification / 15.1: Deacylation / 16.1: Glycosidation / 17.1: Debenzoylation / 18.1: Oxidation / 19.1: Cyclization;
DOI:10.1002/1521-3765(20000901)6:17<3116::AID-CHEM3116>3.0.CO;2-8

Reference yield:

: Trifluoro-methanesulfonate2-[(1R,2R,3S)-2,3-bis-allyloxy-1-benzoyloxy-4-(tert-butyl-diphenyl-silanyloxy)-butyl]-3-methyl-thiazol-3-ium;

: 256342-09-3
C₅₅H₈₄O₁₄Si₂

Guidance literature:: Multi-step reaction with 18 steps

1.1: NaBH₄ / methanol / 0.5 h / 0 °C

1.2: H₂O; CuCl₂; CuO / acetonitrile / 2 h / 25 °C

2.1: 10.97 g / TBAF; AcOH / 2 h / 25 °C

3.1: 85 percent / DBU / CH₂Cl₂ / 0.5 h / 0 °C

4.1: nBu₂SnO / methanol / 3 h / Heating

4.2: TMSOTf / CH₂Cl₂ / 12 h / 0 - 25 °C

4.3: 10.82 g / PPTS; MeOH / 1 h / 25 °C

5.1: 87 percent / NaH / dimethylformamide / 1 h / 0 - 25 °C

6.1: 95 percent / NaOH; MeOH / diethyl ether / 1 h / 25 °C

7.1: NaH / dimethylformamide / 0.08 h / 0 °C

7.2: 90 percent / nBu₄NI / dimethylformamide / 4 h / 0 - 25 °C

8.1: 91 percent / DDQ; H₂O / CH₂Cl₂ / 1 h / 0 - 25 °C

9.1: 97 percent / 2,6-lutidine / CH₂Cl₂ / 1 h / 0 - 25 °C

10.1: DABCO / [(Ph₃P)3RhCl] / aq. ethanol / 2 h / Heating

11.1: 9.27 g / NMO; OsO₄; H₂O / acetone / 8 h / 25 °C

12.1: nBu₂SnO / toluene / 3 h / Heating

12.2: toluene / 1 h / 0 - 25 °C

13.1: 96 percent / Et₃N; DMAP / CH₂Cl₂ / 2 h / 0 - 25 °C

14.1: 96 percent / Et₃N; MeOH / CH₂Cl₂ / 6 h / 40 °C

15.1: 92 percent / SnCl₂; molecular sieves 4 Angstroem / diethyl ether / 3 h / 0 - 25 °C

16.1: 98 percent / K₂CO₃; MeOH / diethyl ether / 12 h / 25 °C

17.1: aq. NaIO₄; NaHCO₃ / methanol; CH₂Cl₂ / 2 h / 25 °C

18.1: 430 mg / iPr₂NH; vinyl acetate / toluene / 12 h / 140 °C

With 1,4-diaza-bicyclo[2.2.2]octane; 2,6-dimethylpyridine; methanol; dmap; sodium hydroxide; sodium tetrahydroborate; sodium periodate; osmium(VIII) oxide; vinyl acetate; N-methyl-2-indolinone; 4 A molecular sieve; tetrabutyl ammonium fluoride; water; sodium hydride; di(n-butyl)tin oxide; sodium hydrogencarbonate; potassium carbonate; acetic acid; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; diisopropylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; tin(ll) chloride; Wilkinson's catalyst; In methanol; diethyl ether; ethanol; dichloromethane; N,N-dimethyl-formamide; acetone; toluene; 1.1: Reduction / 1.2: Ring cleavage / 2.1: Cyclization / 3.1: Addition / 4.1: Cyclization / 4.2: Ring cleavage / 4.3: Methanolysis / 5.1: Methylation / 6.1: Debenzoylation / 7.1: Metallation / 7.2: Etherification / 8.1: Oxidation / 9.1: Etherification / 10.1: Isomerization / 11.1: Oxidation / 12.1: Cyclization / 12.2: Ring cleavage / 13.1: Esterification / 14.1: Deacylation / 15.1: Glycosidation / 16.1: Debenzoylation / 17.1: Oxidation / 18.1: Cyclization;
DOI:10.1002/1521-3765(20000901)6:17<3116::AID-CHEM3116>3.0.CO;2-8