cis-[PtCl₂(NCEt)(PPh₃)]

Base Information

• Chemical Name: cis-[PtCl₂(NCEt)(PPh₃)]
• CAS No.: 1354395-23-5
• Molecular Formula: C₂₁H₂₀Cl₂NPPt
• Molecular Weight: 583.356
• Mol file: 1354395-23-5.mol

Synonyms:cis-[PtCl₂(NCEt)(PPh₃)]

Chemical Property of cis-[PtCl₂(NCEt)(PPh₃)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-[PtCl₂(NCEt)(PPh₃)]

There total 7 articles about cis-[PtCl₂(NCEt)(PPh₃)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

[PtCl2(propionitrile)2] (28005-97-2,146143-88-6,15617-14-8) + triphenylphosphine (603-35-0) → cis-[PtCl2(NCEt)(PPh3)] (1354395-23-5) + trans-[PtCl2(triphenylphosphine)(propionitrile)] (1354395-23-5)

Guidance literature:

In further solvent(s); (N2); a mixt. of Pt complex, P(C6H5)3 and C2H5CN heated at 145°C in a sealed tube for 12 h; cooled slowly to room temp., filtered, dried (vac.); elem. anal.;

DOI:10.1039/c1dt11709b

Reference yield: 68.0%

[PtCl2(propionitrile)2] (28005-97-2,146143-88-6,15617-14-8) + triphenylphosphine (603-35-0) → cis-[PtCl2(NCEt)(PPh3)] (1354395-23-5) + trans-[PtCl2(triphenylphosphine)(propionitrile)] (1354395-23-5)

Guidance literature:

In further solvent(s); (N2); a mixt. of Pt complex, P(C6H5)3 and C2H5CN heated at 145°C in a sealed tube for 12 h; cooled slowly to room temp., filtered, dried (vac.); elem. anal.;

DOI:10.1039/c1dt11709b

Reference yield:

triphenylphosphine (603-35-0) → trans-[PtCl2(triphenylphosphine)(propionitrile)] (1354395-23-5)

Guidance literature:

Multi-step reaction with 3 steps

1: further solvent(s)

2: toluene

3: neat (no solvent)

In toluene;

DOI:10.1039/c1dt11709b

upstream raw materials:

[PtCl₂(propionitrile)₂]

triphenylphosphine

propiononitrile

cis-[PtCl₂(NCCH₃)(PPh₃)]

Downstream raw materials:

trans-[PtCl₂(NCMe)(PPh₃)]

cis-triphenylphosphinecarbonylplatinum(II) dichloride

C₂₇H₃₅ClN₂OPPt

[SP₄-4]-[PtCl(CONEt₂)(NHEt₂)(PPh₃)]

Refernces