2,3,15,16-tetrakis(2,6-dimethylphenyloxy)-8,21-dihydroxy-10,23-dioxo-28,30-dicarbahemiporphyrazine

Base Information

• Chemical Name: 2,3,15,16-tetrakis(2,6-dimethylphenyloxy)-8,21-dihydroxy-10,23-dioxo-28,30-dicarbahemiporphyrazine
• CAS No.: 1352721-88-0
• Molecular Formula: C₆₀H₄₈N₆O₈
• Molecular Weight: 981.077
• Mol file: 1352721-88-0.mol

Synonyms:2,3,15,16-tetrakis(2,6-dimethylphenyloxy)-8,21-dihydroxy-10,23-dioxo-28,30-dicarbahemiporphyrazine

Chemical Property of 2,3,15,16-tetrakis(2,6-dimethylphenyloxy)-8,21-dihydroxy-10,23-dioxo-28,30-dicarbahemiporphyrazine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of 2,3,15,16-tetrakis(2,6-dimethylphenyloxy)-8,21-dihydroxy-10,23-dioxo-28,30-dicarbahemiporphyrazine

There total 2 articles about 2,3,15,16-tetrakis(2,6-dimethylphenyloxy)-8,21-dihydroxy-10,23-dioxo-28,30-dicarbahemiporphyrazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.2%

5,6-bis(2’,6’-dimethylphenoxyl)-1,3-diimino isoindoline (1352721-90-4) + 4,6-diaminoresorcin dihydrochloride (16523-31-2) → 2,3,15,16-tetrakis(2,6-dimethylphenyloxy)-8,21-dihydroxy-10,23-dioxo-28,30-dicarbahemiporphyrazine (1352721-88-0) + 2,3,15,16-tetrakis(2,6-dimethylphenyloxy)-8,10,21,23-tetrahydroxy-28,30-dicarbahemiporphyrazine (1352721-86-8)

Guidance literature:

With triethylamine; In ethanol; at 80 ℃; for 24h; Inert atmosphere;

DOI:10.1021/ja210410c

Reference yield: 70.2%

2,3,15,16-tetrakis(2,6-dimethylphenyloxy)-8,10,21,23-tetrahydroxy-28,30-dicarbahemiporphyrazine (1352721-86-8) → 2,3,15,16-tetrakis(2,6-dimethylphenyloxy)-8,21-dihydroxy-10,23-dioxo-28,30-dicarbahemiporphyrazine (1352721-88-0)

Guidance literature:

With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In chloroform; at 20 ℃; for 0.416667h;

DOI:10.1021/ja210410c

Reference yield: 51.0%

2,3,15,16-tetrakis(2,6-dimethylphenyloxy)-8,21-dihydroxy-10,23-dioxo-28,30-dicarbahemiporphyrazine (1352721-88-0) + bis(dibenzylideneacetone)-palladium(0) (32005-36-0) → C60H46N6O8Pd

Guidance literature:

In dichloromethane; at 20 ℃; for 2h; Inert atmosphere;

DOI:10.1142/S1088424614500667

upstream raw materials:

5,6-bis(2’,6’-dimethylphenoxyl)-1,3-diimino isoindoline

4,6-diaminoresorcin dihydrochloride

2,3,15,16-tetrakis(2,6-dimethylphenyloxy)-8,10,21,23-tetrahydroxy-28,30-dicarbahemiporphyrazine