Re(C₃(OH)(C₆H₅)2)(CO)2(CH₃C(CH₂P(C₆H₅)2)3)

Base Information

• Chemical Name: Re(C₃(OH)(C₆H₅)2)(CO)2(CH₃C(CH₂P(C₆H₅)2)3)
• CAS No.: 380907-37-9
• Molecular Formula: C₅₈H₅₀O₃P₃Re
• Molecular Weight: 1074.16

Synonyms:Re(C₃(OH)(C₆H₅)2)(CO)2(CH₃C(CH₂P(C₆H₅)2)3)

Chemical Property of Re(C₃(OH)(C₆H₅)2)(CO)2(CH₃C(CH₂P(C₆H₅)2)3)

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Technology Process of Re(C₃(OH)(C₆H₅)2)(CO)2(CH₃C(CH₂P(C₆H₅)2)3)

There total 1 articles about Re(C₃(OH)(C₆H₅)2)(CO)2(CH₃C(CH₂P(C₆H₅)2)3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

[(1,1,1-tris(diphenylphosphinomethyl)ethane)Re(CO)2(=C=C=CPh2)](OTf) + potassium hydroxide → Re(C3(OH)(C6H5)2)(CO)2(CH3C(CH2P(C6H5)2)3) (380907-37-9) + Re(C(OH)C2(C6H5)2)(CO)2(CH3C(CH2P(C6H5)2)3)

Guidance literature:

In dichloromethane; water; under N2, standard Schlenk techniques; soln. of Re complex in CH2Cl2 added slowly to soln. of KOH in distd. water under stirring; stirred for ca. 1.5 h; CH2Cl2 layer sepd. from aq. layer; dried over Na2SO4; filtered; solvent removed under reduced pressure; washed with H2O, isopropylic alcohol andn-hexane; dried in N2 stream; elem. anal.;

DOI:10.1039/b103293n

Reference yield: 99.0%

Re(C3(OH)(C6H5)2)(CO)2(CH3C(CH2P(C6H5)2)3) (380907-37-9) → Re(C3(C6H5)2)(CO)2(CH3C(CH2P(C6H5)2)3)(1+)

Guidance literature:

With HOC(CF₃)3; In dichloromethane-d2; under N2, in NMR tube; 10 equiv. of HOC(CF3)3 syringed into soln. of Re complex in CD2Cl2 cooled to -78°C (dry ice-acetone bath); heated to -20°C; not isolated; detd. by (31)P NMR spectroscopy;

DOI:10.1039/b103293n

Reference yield: 99.0%

Re(C3(OH)(C6H5)2)(CO)2(CH3C(CH2P(C6H5)2)3) (380907-37-9) + 1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol (2378-02-1) → Re(CCHC(OH)(C6H5)2)(CO)2(CH3C(CH2P(C6H5)2)3)(1+)

Guidance literature:

In dichloromethane-d2; under N2, in NMR tube; 10 equiv. of HOC(CF3)3 syringed into soln. of Re complex in CD2Cl2 cooled to -78°C (dry ice-acetone bath); not isolated; detd. by (31)P NMR spectroscopy;

DOI:10.1039/b103293n

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