4-methyl-4-(3-methyl-2,3-epoxybutanyl)-2-cyclohexenone

Base Information

• Chemical Name: 4-methyl-4-(3-methyl-2,3-epoxybutanyl)-2-cyclohexenone
• CAS No.: 253317-06-5
• Molecular Formula: C₁₂H₁₈O₂
• Molecular Weight: 194.274
• Mol file: 253317-06-5.mol

Synonyms:4-methyl-4-(3-methyl-2,3-epoxybutanyl)-2-cyclohexenone

Chemical Property of 4-methyl-4-(3-methyl-2,3-epoxybutanyl)-2-cyclohexenone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-methyl-4-(3-methyl-2,3-epoxybutanyl)-2-cyclohexenone

There total 2 articles about 4-methyl-4-(3-methyl-2,3-epoxybutanyl)-2-cyclohexenone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

4-methyl-4-(3-methyl-2-butenyl)-2-cyclohexenone (253317-05-4) → 4-methyl-4-(3-methyl-2,3-epoxybutanyl)-2-cyclohexenone (253317-06-5)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; urea;

DOI:10.1021/jo991115s

Reference yield:

5-(1-Hydroxy-1-methyl-aethyl)-1-methyl-4-methoxy-bicyclo-<2.2.2>-oct-2-en (5502-17-0) → 4-methyl-4-(3-methyl-2,3-epoxybutanyl)-2-cyclohexenone (253317-06-5)

Guidance literature:

Multi-step reaction with 2 steps

1: 63 percent / aq. HClO₄ / acetic acid / 0.75 h / 20 °C

2: 75 percent / m-CPBA; urea

With perchloric acid; 3-chloro-benzenecarboperoxoic acid; urea; In acetic acid; 1: Hydrolysis / 2: Epoxidation;

DOI:10.1021/jo991115s

Reference yield: 62.0%

4-methyl-4-(3-methyl-2,3-epoxybutanyl)-2-cyclohexenone (253317-06-5) → 4-methyl-4-(3-hydroxy-3-methylbutanyl)-2-cyclohexenol (253317-07-6)

Guidance literature:

With lithium aluminium tetrahydride; In diethyl ether; for 12h; Heating;

DOI:10.1021/jo991115s

upstream raw materials:

4-methyl-4-(3-methyl-2-butenyl)-2-cyclohexenone

5-(1-Hydroxy-1-methyl-aethyl)-1-methyl-4-methoxy-bicyclo-<2.2.2>-oct-2-en

Downstream raw materials:

4-methyl-4-(3-hydroxy-3-methylbutanyl)-2-cyclohexenol

4-methyl-4-(3-hydroxy-3-methylbutanyl)-2-cyclohexen-1-yl acetate