(5E,2'Z)-1-methoxy-4-[6-(4-methyl-pent-2-enyloxy)-hex-5-enyloxymethyl]-benzene

Base Information

Chemical Name:(5E,2'Z)-1-methoxy-4-[6-(4-methyl-pent-2-enyloxy)-hex-5-enyloxymethyl]-benzene
CAS No.:936619-45-3
Molecular Formula:C₂₀H₃₀O₃
Molecular Weight:318.456
Hs Code.:

Synonyms:(5E,2'Z)-1-methoxy-4-[6-(4-methyl-pent-2-enyloxy)-hex-5-enyloxymethyl]-benzene

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Chemical Property of (5E,2'Z)-1-methoxy-4-[6-(4-methyl-pent-2-enyloxy)-hex-5-enyloxymethyl]-benzene

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Technology Process of (5E,2'Z)-1-methoxy-4-[6-(4-methyl-pent-2-enyloxy)-hex-5-enyloxymethyl]-benzene

There total 9 articles about (5E,2'Z)-1-methoxy-4-[6-(4-methyl-pent-2-enyloxy)-hex-5-enyloxymethyl]-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 82290-65-1
(Z)-4-methylpent-2-en-1-ol

: 184370-56-7
(E)-1-(6-iodohex-5-en-1-yloxy)methyl-4-methoxybenzene

: 936619-45-3
(5E,2'Z)-1-methoxy-4-[6-(4-methyl-pent-2-enyloxy)-hex-5-enyloxymethyl]-benzene

: 2-(1-isopropyl-allyl)-6-(4-methoxy-benzyloxy)-hexanal

Guidance literature:: With copper(l) iodide; 3,4,7,8-Tetramethyl-o-phenanthrolin; caesium carbonate; In o-xylene; at 90 ℃; for 60h;
DOI:10.1021/ol0702977

Reference yield:

: 111-29-5
1 ,5-pentanediol

: 936619-45-3
(5E,2'Z)-1-methoxy-4-[6-(4-methyl-pent-2-enyloxy)-hex-5-enyloxymethyl]-benzene

Guidance literature:: Multi-step reaction with 4 steps

1: 89 percent / potassium hydroxide / dimethylsulfoxide / 16 h / 0 - 20 °C

2: 96 percent / oxalyl chloride; dimethyl sulfoxide; triethylamine / CH₂Cl₂ / -78 - 0 °C

3: 72 percent / chromium(III) chloride; superhydride / tetrahydrofuran / 3 h / 0 °C

4: 81 percent / copper(I) iodide; 3,4,7,8-tetramethyl-1,10-phenanthroline; cesium carbonate / o-xylene / 60 h / 90 °C

With potassium hydroxide; copper(l) iodide; oxalyl dichloride; 3,4,7,8-Tetramethyl-o-phenanthrolin; chromium(III) chloride; lithium triethylborohydride; caesium carbonate; dimethyl sulfoxide; triethylamine; In tetrahydrofuran; dichloromethane; o-xylene; dimethyl sulfoxide; 4: Buchwald coupling;
DOI:10.1021/ol0702977

Reference yield:

: 1775-44-6
(Z)-4-methyl-2-pentenoic acid

: 936619-45-3
(5E,2'Z)-1-methoxy-4-[6-(4-methyl-pent-2-enyloxy)-hex-5-enyloxymethyl]-benzene

Guidance literature:: Multi-step reaction with 3 steps

1: diethyl ether

2: 13.2 g / di-isobutylaluminium hydride / CH₂Cl₂; diethyl ether / 1 h / -78 °C

3: 81 percent / copper(I) iodide; 3,4,7,8-tetramethyl-1,10-phenanthroline; cesium carbonate / o-xylene / 60 h / 90 °C

With copper(l) iodide; diisobutylaluminum hydride; 3,4,7,8-Tetramethyl-o-phenanthrolin; caesium carbonate; In diethyl ether; dichloromethane; o-xylene; 3: Buchwald coupling;
DOI:10.1021/ol0702977