Methyl-6-O-<2-azido-2-desoxy-4,6-O-isopropyliden-3-O-<(R)-1-(methoxycarbonyl)ethyl>-β-D-glucopyranosyl>-2,3,4-tri-O-benzyl-α-D-glucopyranosid

Base Information

Chemical Name:Methyl-6-O-<2-azido-2-desoxy-4,6-O-isopropyliden-3-O-<(R)-1-(methoxycarbonyl)ethyl>-β-D-glucopyranosyl>-2,3,4-tri-O-benzyl-α-D-glucopyranosid
CAS No.:106567-79-7
Molecular Formula:C₄₁H₅₁N₃O₁₂
Molecular Weight:777.869
Hs Code.:

Synonyms:Methyl-6-O-<2-azido-2-desoxy-4,6-O-isopropyliden-3-O-<(R)-1-(methoxycarbonyl)ethyl>-β-D-glucopyranosyl>-2,3,4-tri-O-benzyl-α-D-glucopyranosid

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Chemical Property of Methyl-6-O-<2-azido-2-desoxy-4,6-O-isopropyliden-3-O-<(R)-1-(methoxycarbonyl)ethyl>-β-D-glucopyranosyl>-2,3,4-tri-O-benzyl-α-D-glucopyranosid

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Technology Process of Methyl-6-O-<2-azido-2-desoxy-4,6-O-isopropyliden-3-O-<(R)-1-(methoxycarbonyl)ethyl>-β-D-glucopyranosyl>-2,3,4-tri-O-benzyl-α-D-glucopyranosid

There total 4 articles about Methyl-6-O-<2-azido-2-desoxy-4,6-O-isopropyliden-3-O-<(R)-1-(methoxycarbonyl)ethyl>-β-D-glucopyranosyl>-2,3,4-tri-O-benzyl-α-D-glucopyranosid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 53008-65-4,641635-63-4
methyl 2,3,4-tri-O-benzyl-D-glucopyranoside

: 106567-72-0
O-<2-Azido-2-desoxy-4,6-O-isopropyliden-3-O-<(R)-1-(methoxycarbonyl)ethyl>-α-D-glucopyranosyl>-trichloracetimidat

: 106567-79-7
Methyl-6-O-<2-azido-2-desoxy-4,6-O-isopropyliden-3-O-<(R)-1-(methoxycarbonyl)ethyl>-β-D-glucopyranosyl>-2,3,4-tri-O-benzyl-α-D-glucopyranosid

Guidance literature:: With boron trifluoride diethyl etherate; In hexane; dichloromethane; at -10 ℃; for 3h;

Reference yield:

: 99049-68-0
tert-Butyldimethylsilyl-2-azido-2-desoxy-4,6-O-isopropyliden-β-D-glucopyranosid

: 106567-79-7
Methyl-6-O-<2-azido-2-desoxy-4,6-O-isopropyliden-3-O-<(R)-1-(methoxycarbonyl)ethyl>-β-D-glucopyranosyl>-2,3,4-tri-O-benzyl-α-D-glucopyranosid

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) NaH / 1.) DME, room temp.; 2.) 3 h

2: 71 percent / silica gel, (NBu₄)F / tetrahydrofuran / 2 h / -50 °C

3: NaH / CH₂Cl₂

4: 92 percent / BF₃*Et₂₀ / hexane; CH₂Cl₂ / 3 h / -10 °C

With boron trifluoride diethyl etherate; tetrabutyl ammonium fluoride; silica gel; sodium hydride; In tetrahydrofuran; hexane; dichloromethane;

Reference yield:

: 2-Azido-2-desoxy-4,6-isopropyliden-3-O-<(R)-1-(methoxycarbonyl)ethyl>-D-glucopyranose

: 106567-79-7
Methyl-6-O-<2-azido-2-desoxy-4,6-O-isopropyliden-3-O-<(R)-1-(methoxycarbonyl)ethyl>-β-D-glucopyranosyl>-2,3,4-tri-O-benzyl-α-D-glucopyranosid

Guidance literature:: Multi-step reaction with 2 steps

1: NaH / CH₂Cl₂

2: 92 percent / BF₃*Et₂₀ / hexane; CH₂Cl₂ / 3 h / -10 °C

With boron trifluoride diethyl etherate; sodium hydride; In hexane; dichloromethane;