[bis(phenethylcyclopentadienyl)dirhodium tetrachloride]

Base Information

• Chemical Name: [bis(phenethylcyclopentadienyl)dirhodium tetrachloride]
• CAS No.: 155678-56-1
• Molecular Formula: C₃₄H₄₂Cl₄Rh₂
• Molecular Weight: 798.33
• Mol file: 155678-56-1.mol

Synonyms:[bis(phenethylcyclopentadienyl)dirhodium tetrachloride]

Chemical Property of [bis(phenethylcyclopentadienyl)dirhodium tetrachloride]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of [bis(phenethylcyclopentadienyl)dirhodium tetrachloride]

There total 2 articles about [bis(phenethylcyclopentadienyl)dirhodium tetrachloride] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

chloro(1,5-cyclooctadiene)rhodium(I) dimer + (2-(2,3,4,5-tetramethylcyclopenta-2,4-dien-1-yl)-ethyl)benzene → [bis(phenethylcyclopentadienyl)dirhodium tetrachloride] (155678-56-1)

Guidance literature:

With hydrogenchloride; In methanol; at 115 ℃; for 1h; under 7757.43 Torr; Microwave irradiation;

DOI:10.1021/acs.organomet.6b00580

Reference yield: 45.0%

[(C5(CH3)4CH2CH2C6H5)Rh(C5H5)](1+)*PF6(1-)=[(C5H5)Rh(C5(CH3)4CH2CH2C6H5)]PF6 (155678-86-7) + phenyllithium (591-51-5) → [bis(phenethylcyclopentadienyl)dirhodium tetrachloride] (155678-56-1)

Guidance literature:

With hydrogenchloride; In diethyl ether; cyclohexane; water; reaction under N2 or Ar: addn. of LiPh to a suspn. of Rh-compd. in cyclohexane/ether, stirring for 0.5 h at 20°C, addn. of water, filtn., stream of HCl-gas is passed through this soln. for 5 min; elem. anal.;

Reference yield: 92.0%

[bis(phenethylcyclopentadienyl)dirhodium tetrachloride] (155678-56-1) + sodium acetylacetonate (15435-71-9,1118-67-8) → C22H28ClO2Rh

Guidance literature:

In acetone; for 2h;

DOI:10.1021/acs.organomet.7b00742

upstream raw materials:

[(C₅(CH₃)4CH₂CH₂C₆H₅)Rh(C₅H₅)]⁽¹⁺⁾*PF₆^(1-)=[(C₅H₅)Rh(C₅(CH₃)4CH₂CH₂C₆H₅)]PF₆

phenyllithium