(S,Z)-tert-butyl(1-(4-methoxybenzyloxy)undec-3-en-2-yloxy)diphenylsilane

Base Information

Chemical Name:(S,Z)-tert-butyl(1-(4-methoxybenzyloxy)undec-3-en-2-yloxy)diphenylsilane
CAS No.:1350928-35-6
Molecular Formula:C₃₅H₄₈O₃Si
Molecular Weight:544.85
Hs Code.:

Synonyms:(S,Z)-tert-butyl(1-(4-methoxybenzyloxy)undec-3-en-2-yloxy)diphenylsilane

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Chemical Property of (S,Z)-tert-butyl(1-(4-methoxybenzyloxy)undec-3-en-2-yloxy)diphenylsilane

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Technology Process of (S,Z)-tert-butyl(1-(4-methoxybenzyloxy)undec-3-en-2-yloxy)diphenylsilane

There total 10 articles about (S,Z)-tert-butyl(1-(4-methoxybenzyloxy)undec-3-en-2-yloxy)diphenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1353990-64-3
C₂₇H₃₂O₄Si

: 42036-78-2
n-octyltriphenylphosphoniumbromide

: 1350928-35-6
(S,Z)-tert-butyl(1-(4-methoxybenzyloxy)undec-3-en-2-yloxy)diphenylsilane

: (S,E)-tert-butyl(1-(4-methoxybenzyloxy)undec-3-en-2-yloxy)diphenylsilane

Guidance literature:: n-octyltriphenylphosphoniumbromide; With n-butyllithium; In tetrahydrofuran; hexane; at 0 ℃; for 0.0833333h; Inert atmosphere;

C₂₇H₃₂O₄Si; In tetrahydrofuran; hexane; dimethyl sulfoxide; at 0 - 20 ℃; for 0.5h; optical yield given as %de; Inert atmosphere;
DOI:10.1016/j.tet.2011.10.058

Reference yield:

: C₂₈H₃₆O₅Si

: 1350928-35-6
(S,Z)-tert-butyl(1-(4-methoxybenzyloxy)undec-3-en-2-yloxy)diphenylsilane

Guidance literature:: Multi-step reaction with 2 steps

1.1: SiO₂-supported NaIO₄ / dichloromethane / 0.5 h / 0 - 20 °C / Inert atmosphere

2.1: n-butyllithium / tetrahydrofuran; hexane / 0.08 h / 0 °C / Inert atmosphere

2.2: 0.5 h / 0 - 20 °C / Inert atmosphere

With n-butyllithium; SiO₂-supported NaIO₄; In tetrahydrofuran; hexane; dichloromethane; 2.2: Wittig reaction;
DOI:10.1016/j.tet.2011.10.058

Reference yield:

: 1350928-34-5
(S)-tert-butyl(1-(4-methoxybenzyloxy)but-3-en-2-yloxy)diphenylsilane

: 1350928-35-6
(S,Z)-tert-butyl(1-(4-methoxybenzyloxy)undec-3-en-2-yloxy)diphenylsilane

Guidance literature:: Multi-step reaction with 3 steps

1.1: osmium(VIII) oxide; water; 4-methylmorpholine N-oxide / acetone; tert-butyl alcohol / 8 h / 20 °C / Inert atmosphere

1.2: 1 h / 20 °C / Inert atmosphere

2.1: SiO₂-supported NaIO₄ / dichloromethane / 0.5 h / 0 - 20 °C / Inert atmosphere

3.1: n-butyllithium / tetrahydrofuran; hexane / 0.08 h / 0 °C / Inert atmosphere

3.2: 0.5 h / 0 - 20 °C / Inert atmosphere

With osmium(VIII) oxide; n-butyllithium; SiO₂-supported NaIO₄; water; 4-methylmorpholine N-oxide; In tetrahydrofuran; hexane; dichloromethane; acetone; tert-butyl alcohol; 1.1: Upjohn dihydroxylation / 3.2: Wittig reaction;
DOI:10.1016/j.tet.2011.10.058