3-O-allyl-2-O-[2,3,4-tri-O-benzyl-6-O-(9H-fluoren-9-ylmethyloxycarbohyl)-α-D-glucopyranosyl]-1-O-(tert-butyldiphenylsilyl)-sn-glycerol

Base Information

Chemical Name:3-O-allyl-2-O-[2,3,4-tri-O-benzyl-6-O-(9H-fluoren-9-ylmethyloxycarbohyl)-α-D-glucopyranosyl]-1-O-(tert-butyldiphenylsilyl)-sn-glycerol
CAS No.:1384160-44-4
Molecular Formula:C₆₄H₆₈O₁₀Si
Molecular Weight:1025.32
Hs Code.:

Synonyms:3-O-allyl-2-O-[2,3,4-tri-O-benzyl-6-O-(9H-fluoren-9-ylmethyloxycarbohyl)-α-D-glucopyranosyl]-1-O-(tert-butyldiphenylsilyl)-sn-glycerol

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Chemical Property of 3-O-allyl-2-O-[2,3,4-tri-O-benzyl-6-O-(9H-fluoren-9-ylmethyloxycarbohyl)-α-D-glucopyranosyl]-1-O-(tert-butyldiphenylsilyl)-sn-glycerol

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Technology Process of 3-O-allyl-2-O-[2,3,4-tri-O-benzyl-6-O-(9H-fluoren-9-ylmethyloxycarbohyl)-α-D-glucopyranosyl]-1-O-(tert-butyldiphenylsilyl)-sn-glycerol

There total 1 articles about 3-O-allyl-2-O-[2,3,4-tri-O-benzyl-6-O-(9H-fluoren-9-ylmethyloxycarbohyl)-α-D-glucopyranosyl]-1-O-(tert-butyldiphenylsilyl)-sn-glycerol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 1384160-41-1
C₅₀H₄₄F₃NO₈

: 544686-87-5
(S)-(-)-1-allyl-3-tert-butyldiphenylsilyl-sn-glycerol

: 3-O-allyl-2-O-[2,3,4-tri-O-benzyl-6-O-(9H-fluoren-9-ylmethyloxycarbohyl)-β-D-glucopyranosyl]-1-O-(tert-butyldiphenylsilyl)-sn-glycerol

: 1384160-44-4
3-O-allyl-2-O-[2,3,4-tri-O-benzyl-6-O-(9H-fluoren-9-ylmethyloxycarbohyl)-α-D-glucopyranosyl]-1-O-(tert-butyldiphenylsilyl)-sn-glycerol

Guidance literature:: With trifluorormethanesulfonic acid; In diethyl ether; at 0 ℃; for 0.416667h; optical yield given as %de; diastereoselective reaction; Inert atmosphere;
DOI:10.1016/j.carres.2012.02.023

Reference yield: 94.0%

: 1384160-44-4
3-O-allyl-2-O-[2,3,4-tri-O-benzyl-6-O-(9H-fluoren-9-ylmethyloxycarbohyl)-α-D-glucopyranosyl]-1-O-(tert-butyldiphenylsilyl)-sn-glycerol

: 1384160-45-5
3-O-allyl-2-O-(2,3,4-tri-O-benzyl-α-D-glucopyranosyl)-1-O-(tert-butyldiphenylsilyl)-sn-glycerol

Guidance literature:: With 1,8-diazabicyclo[5.4.0]undec-7-ene; In dichloromethane; at 20 ℃; for 0.25h; Inert atmosphere;
DOI:10.1016/j.carres.2012.02.023

Reference yield:

: 1384160-44-4
3-O-allyl-2-O-[2,3,4-tri-O-benzyl-6-O-(9H-fluoren-9-ylmethyloxycarbohyl)-α-D-glucopyranosyl]-1-O-(tert-butyldiphenylsilyl)-sn-glycerol

: 1384160-42-2
3-O-allyl-2-O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-1-O-(tert-butyldiphenylsilyl)-sn-glycerol

Guidance literature:: Multi-step reaction with 2 steps

1: 1,8-diazabicyclo[5.4.0]undec-7-ene / dichloromethane / 0.25 h / 20 °C / Inert atmosphere

2: sodium hydride / N,N-dimethyl-formamide; mineral oil / 0 - 20 °C / Inert atmosphere

With sodium hydride; 1,8-diazabicyclo[5.4.0]undec-7-ene; In dichloromethane; N,N-dimethyl-formamide; mineral oil;
DOI:10.1016/j.carres.2012.02.023