1-[2-(tributylstannyl)allyl]phenoxide

Base Information

• Chemical Name: 1-[2-(tributylstannyl)allyl]phenoxide
• CAS No.: 119649-70-6
• Molecular Formula: C₂₁H₃₆OSn
• Molecular Weight: 423.226
• Mol file: 119649-70-6.mol

Synonyms:1-[2-(tributylstannyl)allyl]phenoxide

Chemical Property of 1-[2-(tributylstannyl)allyl]phenoxide

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 1-[2-(tributylstannyl)allyl]phenoxide

There total 2 articles about 1-[2-(tributylstannyl)allyl]phenoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-phenoxy-2-propyne (13610-02-1) + tri-n-butyl-tin hydride (688-73-3) → (Z)-(3-phenoxyprop-1-ene-1,2-diyl)bis(tributylstannane) (164169-33-9,197857-00-4,164169-32-8) + 1-[2-(tributylstannyl)allyl]phenoxide (119649-70-6)

Guidance literature:

With porous vinyl functionalized tri(2-methoxyphenyl)phosphine derived polymer supported palladium; In tetrahydrofuran; at 45 ℃; for 24h; Overall yield = 63 percent; stereoselective reaction; Schlenk technique; Sealed tube;

DOI:10.1016/j.chempr.2020.06.020

Reference yield:

1-phenoxy-2-propyne (13610-02-1) + tri-n-butyl-tin hydride (688-73-3) → 1-[2-(tributylstannyl)allyl]phenoxide (119649-70-6)

Guidance literature:

tris(t-butyl isocyanide)tricarbonylmolybdenum(O); In tetrahydrofuran; Sn compd. (2 equiv.) was added to soln. of ether in THF in presence of Mo catalyst; heated at 60°C for 22 h;

DOI:10.1002/anie.200705976

Reference yield: 77.0%

1-[2-(tributylstannyl)allyl]phenoxide (119649-70-6) + trimethylsilyltributyltin (17955-46-3) → 2,3-bis(trimethylsilyl)prop-1-ene (17891-65-5)

Guidance literature:

tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; at 60 ℃; for 18h;

DOI:10.1002/anie.200705976

upstream raw materials:

1-phenoxy-2-propyne

tri-n-butyl-tin hydride

Downstream raw materials:

2,3-bis(trimethylsilyl)prop-1-ene