<(1S)-<1-²H>-2-furfuryl> (2S)-2-acetoxy-2-phenylethanoate

Base Information

Chemical Name:<(1S)-<1-²H>-2-furfuryl> (2S)-2-acetoxy-2-phenylethanoate
CAS No.:118070-13-6
Molecular Formula:C₁₅H₁₄O₅
Molecular Weight:275.265
Hs Code.:

<(1S)-<1-<sup>2</sup>H>-2-furfuryl> (2S)-2-acetoxy-2-phenylethanoate

Synonyms:<(1S)-<1-²H>-2-furfuryl> (2S)-2-acetoxy-2-phenylethanoate

Suppliers and Price of <(1S)-<1-²H>-2-furfuryl> (2S)-2-acetoxy-2-phenylethanoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of <(1S)-<1-²H>-2-furfuryl> (2S)-2-acetoxy-2-phenylethanoate

Chemical Property:

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Technology Process of <(1S)-<1-²H>-2-furfuryl> (2S)-2-acetoxy-2-phenylethanoate

There total 5 articles about <(1S)-<1-²H>-2-furfuryl> (2S)-2-acetoxy-2-phenylethanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.2%

: 7322-88-5
(S)-acetylmandelic acid

: 112302-64-4
(1S)-<1-²H>furfurylalcohol

: 118070-13-6
<(1S)-<1-²H>-2-furfuryl> (2S)-2-acetoxy-2-phenylethanoate

Guidance literature:: With dicyclohexyl-carbodiimide; dmap; In dichloromethane; 0 degC, 4 h then 25 degC, 18 h;
DOI:10.1016/S0040-4020(01)86064-6

Reference yield:

: 98-01-1
furfural

: 118070-13-6
<(1S)-<1-²H>-2-furfuryl> (2S)-2-acetoxy-2-phenylethanoate

Guidance literature:: Multi-step reaction with 5 steps

1: 75 percent / BF₃*Et₂O / CH₂Cl₂ / 0 degC, 1 h then 25 degC, 18 h

2: 84 percent / n-butyllithium, deuterium oxide / tetrahydrofuran; hexane / -50 degC, 6 h then allowed to warm to 25 degC

3: 71 percent / mercuric oxide, mercuric chloride / methanol; H₂O / 4 h / Heating

4: 75 percent / (R)-(+)-B-isopinocampheyl-9-borabicyclo<3.3.1>nonane / tetrahydrofuran / 25 degC, 4 h then 75 degC, 1 h

5: 81.2 percent / DCC / DMAP / CH₂Cl₂ / 0 degC, 4 h then 25 degC, 18 h

With n-butyllithium; B-isopinocampheyl-9-borabicyclo[3.3.1]nonane; boron trifluoride diethyl etherate; water-d2; dicyclohexyl-carbodiimide; mercury dichloride; mercury(II) oxide; dmap; In tetrahydrofuran; methanol; hexane; dichloromethane; water;
DOI:10.1016/S0040-4020(01)86064-6

Reference yield:

: 67421-75-4
2-(1,3-dithian-2-yl)furan

: 118070-13-6
<(1S)-<1-²H>-2-furfuryl> (2S)-2-acetoxy-2-phenylethanoate

Guidance literature:: Multi-step reaction with 4 steps

1: 84 percent / n-butyllithium, deuterium oxide / tetrahydrofuran; hexane / -50 degC, 6 h then allowed to warm to 25 degC

2: 71 percent / mercuric oxide, mercuric chloride / methanol; H₂O / 4 h / Heating

3: 75 percent / (R)-(+)-B-isopinocampheyl-9-borabicyclo<3.3.1>nonane / tetrahydrofuran / 25 degC, 4 h then 75 degC, 1 h

4: 81.2 percent / DCC / DMAP / CH₂Cl₂ / 0 degC, 4 h then 25 degC, 18 h

With n-butyllithium; B-isopinocampheyl-9-borabicyclo[3.3.1]nonane; water-d2; dicyclohexyl-carbodiimide; mercury dichloride; mercury(II) oxide; dmap; In tetrahydrofuran; methanol; hexane; dichloromethane; water;
DOI:10.1016/S0040-4020(01)86064-6