(R)-(-)-5-benzyloxy-2-[2'-(2,2,2-trichloroethoxycarbonyl)oxy]propyl-1,4-naphthalenedione

Base Information

Chemical Name:(R)-(-)-5-benzyloxy-2-[2'-(2,2,2-trichloroethoxycarbonyl)oxy]propyl-1,4-naphthalenedione
CAS No.:394738-54-6
Molecular Formula:C₂₃H₁₉Cl₃O₆
Molecular Weight:497.759
Hs Code.:

Synonyms:(R)-(-)-5-benzyloxy-2-[2'-(2,2,2-trichloroethoxycarbonyl)oxy]propyl-1,4-naphthalenedione

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (R)-(-)-5-benzyloxy-2-[2'-(2,2,2-trichloroethoxycarbonyl)oxy]propyl-1,4-naphthalenedione

Chemical Property:

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Technology Process of (R)-(-)-5-benzyloxy-2-[2'-(2,2,2-trichloroethoxycarbonyl)oxy]propyl-1,4-naphthalenedione

There total 1 articles about (R)-(-)-5-benzyloxy-2-[2'-(2,2,2-trichloroethoxycarbonyl)oxy]propyl-1,4-naphthalenedione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 394738-53-5
Carbonic acid (R)-2-(5-benzyloxy-1-oxo-1,2,3,4-tetrahydro-naphthalen-2-yl)-1-methyl-ethyl ester 2,2,2-trichloro-ethyl ester

: 394738-54-6
(R)-(-)-5-benzyloxy-2-[2'-(2,2,2-trichloroethoxycarbonyl)oxy]propyl-1,4-naphthalenedione

Guidance literature:: With selenium(IV) oxide; In 1,4-dioxane; for 15h; Heating;
DOI:10.1002/1099-0690(200111)2001:22<4313::AID-EJOC4313>3.0.CO;2-J

Reference yield: 81.0%

: 394738-54-6
(R)-(-)-5-benzyloxy-2-[2'-(2,2,2-trichloroethoxycarbonyl)oxy]propyl-1,4-naphthalenedione

: (S)-(-)-5-benzyloxy-2-(2'-hydroxypropyl)-1,4-naphthalenediol

Guidance literature:: With zinc; In acetic acid; at 20 ℃; for 2.33333h;
DOI:10.1002/1099-0690(200111)2001:22<4313::AID-EJOC4313>3.0.CO;2-J

Reference yield:

: 394738-54-6
(R)-(-)-5-benzyloxy-2-[2'-(2,2,2-trichloroethoxycarbonyl)oxy]propyl-1,4-naphthalenedione

: (S)-(-)-6-benzyloxy-2,3-dihydro-2-methylnaphtho[1,2-b]furan-5-ol

Guidance literature:: Multi-step reaction with 2 steps

1: 81 percent / powdered Zn / acetic acid / 2.33 h / 20 °C

2: 19 percent / Ph₃P; DEAD / tetrahydrofuran / 21 h / 20 °C

With triphenylphosphine; zinc; diethylazodicarboxylate; In tetrahydrofuran; acetic acid;
DOI:10.1002/1099-0690(200111)2001:22<4313::AID-EJOC4313>3.0.CO;2-J