Triamylamine

Base Information

• Chemical Name: Triamylamine
• CAS No.: 621-77-2
• Molecular Formula: C15H33N
• Molecular Weight: 227.434
• Hs Code.: 2921199090
• European Community (EC) Number: 210-705-7
• NSC Number: 406964
• UN Number: 2735
• DSSTox Substance ID: DTXSID0026177
• Nikkaji Number: J121.777A
• Wikidata: Q81983942
• Mol file: 621-77-2.mol

Synonyms:Triamylamine;Tripentylamine;621-77-2;Tri-n-pentylamine;1-Pentanamine, N,N-dipentyl-;N,N-dipentylpentan-1-amine;TRI-N-AMYLAMINE;CCRIS 4877;EINECS 210-705-7;214290-37-6;NSC 406964;AI3-11530;tripentyl amine;1-Pentanamine,N-dipentyl-;Triamylamine, mixed isomers;SCHEMBL36548;N(CCCCC)(CCCCC)CCCCC;N,N-Dipentyl-1-pentanamine #;DTXSID0026177;MFCD00015270;NSC406964;AKOS015894783;Tripentylamine,98%,mixture of isomers;LS-1488;NSC-406964;CS-0199454;FT-0704851;T1177;E78242

Chemical Property of Triamylamine

Chemical Property:

• Appearance/Colour: clear colorless to yellow liquid with an amine odor
• Vapor Pressure: 1 mm Hg ( 20 °C)
• Melting Point: -61.15°C (estimate)
• Refractive Index: n20/D 1.436(lit.)
• Boiling Point: 242.5 °C at 760 mmHg
• PKA: 9.99±0.50(Predicted)
• Flash Point: 97.8 °C
• PSA: 3.24000
• Density: 0.802 g/cm³
• LogP: 4.85900
• Water Solubility.: Insoluble in water
• XLogP3: 5.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 12
• Exact Mass: 227.261300057
• Heavy Atom Count: 16
• Complexity: 98.8
• Transport DOT Label: Corrosive

Purity/Quality:

99% ^*data from raw suppliers

Triamylamine >98.0%(GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi,C
• Hazard Codes: Xi,C
• Statements: 36/37/38-34-22
• Safety Statements: 26-36-45-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Nitrogen Compounds -> Amines, Aliphatic
• Canonical SMILES: CCCCCN(CCCCC)CCCCC
• Uses: Corrosion inhibitor, insecticidal preparations.

Technology Process of Triamylamine

There total 21 articles about Triamylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

pentanonitrile (110-59-8) → tripentylamine (621-77-2)

Guidance literature:

With palladium 10% on activated carbon; hydrogen; In cyclohexane; at 25 ℃; for 6h; under 760.051 Torr;

DOI:10.1021/acs.joc.7b01823

Reference yield: 68.0%

ethyl valerimidate (999-09-7) → tripentylamine (621-77-2) + Di-n-amylamine (2050-92-2)

Guidance literature:

With platinum on carbon; hydrogen; at 25 ℃; for 16h; under 7500.75 Torr;

DOI:10.1002/cctc.201701287

Reference yield: 63.0%

pentanonitrile (110-59-8) → tripentylamine (621-77-2) + N-pentylidenepentan-1-amine (65870-64-6) + Di-n-amylamine (2050-92-2)

Guidance literature:

With hydrogen; at 200 ℃;

DOI:10.1134/S1070427217110088

upstream raw materials:

pentanonitrile

1-Chloropentane

Di-n-amylamine

n-butyl magnesium bromide

Downstream raw materials:

pentanonitrile

pentane

2-pentene

perfluorotri-n-pentylamine