(E)-(R)-3-(Dimethyl-phenyl-silanyl)-4-methyl-hex-4-enoic acid 3-anthracen-9-yl-propyl ester

Base Information

• Chemical Name: (E)-(R)-3-(Dimethyl-phenyl-silanyl)-4-methyl-hex-4-enoic acid 3-anthracen-9-yl-propyl ester
• CAS No.: 867370-98-7
• Molecular Formula: C₃₂H₃₆O₂Si
• Molecular Weight: 480.722
• Mol file: 867370-98-7.mol

Synonyms:(E)-(R)-3-(Dimethyl-phenyl-silanyl)-4-methyl-hex-4-enoic acid 3-anthracen-9-yl-propyl ester

Chemical Property of (E)-(R)-3-(Dimethyl-phenyl-silanyl)-4-methyl-hex-4-enoic acid 3-anthracen-9-yl-propyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (E)-(R)-3-(Dimethyl-phenyl-silanyl)-4-methyl-hex-4-enoic acid 3-anthracen-9-yl-propyl ester

There total 1 articles about (E)-(R)-3-(Dimethyl-phenyl-silanyl)-4-methyl-hex-4-enoic acid 3-anthracen-9-yl-propyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ω-(anthracene-9-yl)propanol (22689-05-0) + (E)-(R)-3-(Dimethyl-phenyl-silanyl)-4-methyl-hex-4-enoic acid methyl ester (173673-08-0) → (E)-(R)-3-(Dimethyl-phenyl-silanyl)-4-methyl-hex-4-enoic acid 3-anthracen-9-yl-propyl ester (867370-98-7)

Guidance literature:

With 1,3-dichlorotetrabutyldistannoxane; In chlorobenzene; at 160 ℃; for 0.333333h; microwave irradiation;

DOI:10.1021/ol0516723

Reference yield:

((1S,2R,3R,4S)-1,3,5,5-Tetramethoxy-2,4-dimethyl-pentyl)-benzene (867371-03-7) + (E)-(R)-3-(Dimethyl-phenyl-silanyl)-4-methyl-hex-4-enoic acid 3-anthracen-9-yl-propyl ester (867370-98-7) → (E)-(7R,8S,9R,10S)-6,8,10-Trimethoxy-4,5,7,9-tetramethyl-10-phenyl-dec-3-enoic acid 3-anthracen-9-yl-propyl ester

Guidance literature:

With boron trifluoride diethyl etherate; In dichloromethane; at -10 ℃; for 16h;

DOI:10.1021/ol0516723

Reference yield:

((1R,2S,3R,4S)-1,3,5,5-Tetramethoxy-2,4-dimethyl-pentyl)-benzene + (E)-(R)-3-(Dimethyl-phenyl-silanyl)-4-methyl-hex-4-enoic acid 3-anthracen-9-yl-propyl ester (867370-98-7) → (3S,4R,5S,6S,7S,8R)-4,6,8-Trimethoxy-3,5,7-trimethyl-8-phenyl-octan-2-one

Guidance literature:

Multistep reaction;

DOI:10.1021/ol0516723

upstream raw materials:

ω-(anthracene-9-yl)propanol

(E)-(R)-3-(Dimethyl-phenyl-silanyl)-4-methyl-hex-4-enoic acid methyl ester