(OtBu)(NH-4-C₆H₄Me)SiMe₂

Base Information

• Chemical Name: (OtBu)(NH-4-C₆H₄Me)SiMe₂
• CAS No.: 1342872-56-3
• Molecular Formula: C₁₃H₂₃NOSi
• Molecular Weight: 237.417
• Mol file: 1342872-56-3.mol

Synonyms:(OtBu)(NH-4-C₆H₄Me)SiMe₂

Chemical Property of (OtBu)(NH-4-C₆H₄Me)SiMe₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of (OtBu)(NH-4-C₆H₄Me)SiMe₂

There total 1 articles about (OtBu)(NH-4-C₆H₄Me)SiMe₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

tert-butoxy(dimethyl)silyl chloride (58566-07-7) + p-toluidine (106-49-0,12221-03-3) → (OtBu)(NH-4-C6H4Me)SiMe2 (1342872-56-3)

Guidance literature:

p-toluidine; With n-butyllithium; In hexane; at 0 ℃; Inert atmosphere;

tert-butoxy(dimethyl)silyl chloride; In hexane; at 20 ℃; Inert atmosphere;

DOI:10.1016/j.poly.2011.08.011

Reference yield: 80.0%

(OtBu)(NH-4-C6H4Me)SiMe2 (1342872-56-3) + tin(ll) chloride → Sn((CH3)2SiNC6H4CH3OC(CH3)3)2 (1342872-60-9)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; hexane; byproducts: LiCl; (N2 or Ar); dropwise addn. of a soln. of Li compd. in hexanes to a soln.of Si compd. in hexanes at 0°C, reflux for 3 h, cooling to room temp., dropwise addn. to a soln. of SnCl2 in THF at -78°C, stirri ng for 12 h warming to room temp.; evapn. in vac., extn. with hexanes, filtration, concn. in vac., cooling to -21°C for 1 wk; elem. anal.;

DOI:10.1016/j.poly.2011.08.011

Reference yield: 75.0%

ZrCl4(tetrahydrofuran)2 (125410-70-0,125410-71-1,21959-01-3) + (OtBu)(NH-4-C6H4Me)SiMe2 (1342872-56-3) → [Me2Si(OtBu)N(p-C6H4Me)]3ZrCl

Guidance literature:

(OtBu)(NH-4-C₆H₄Me)SiMe₂; With n-butyllithium; In hexane; at 0 ℃; for 3h; Inert atmosphere; Schlenk technique; Reflux;

ZrCl₄(tetrahydrofuran)2; In tetrahydrofuran; hexane; at -78 - 20 ℃; Inert atmosphere; Schlenk technique;

DOI:10.1016/j.jorganchem.2014.11.012

upstream raw materials:

tert-butoxy(dimethyl)silyl chloride

p-toluidine

Downstream raw materials:

(Zn(CH₂CH₃)(OC(CH₃)3Si(CH₃)2NC₆H₄CH₃))2

Sn((CH₃)2SiNC₆H₄CH₃OC(CH₃)3)2