[(8E)-3,8-Dimethyl-12-methylidene-13-oxo-4,14-dioxatricyclo[9.3.0.03,5]tetradec-8-en-10-yl] acetate

Base Information

Chemical Name:[(8E)-3,8-Dimethyl-12-methylidene-13-oxo-4,14-dioxatricyclo[9.3.0.03,5]tetradec-8-en-10-yl] acetate
CAS No.:28272-18-6
Molecular Formula:C₁₇H₂₂O₅
Molecular Weight:306.359
Hs Code.:
ChEMBL ID:CHEMBL1968658
NSC Number:22070
Mol file:28272-18-6.mol

Synonyms:28272-18-6;[(8E)-3,8-Dimethyl-12-methylidene-13-oxo-4,14-dioxatricyclo[9.3.0.03,5]tetradec-8-en-10-yl] acetate;MLS002702827;NSC22070;NSC-22070;CHEMBL1968658;Germacra-4, 1.alpha.,10.alpha.-epoxy-6,8.beta.-dihydroxy-, 12,8-lactone, acetate;Germacra-4, 1.beta.,10-epoxy-6.alpha.,8.alpha.-dihydroxy-, 12,8-lactone, acetate, (E)-;Oxireno[8,2-b]furan-8(2H)-one, 6-(acetyloxy)-1a,3,6,6a,7,9a,10,10a-octahydro-4,10a-dimethyl-7-methylene-, [1aR-(1aR*,4E,6R*,6aR*,9aS*,10aR*)]-

Suppliers and Price of [(8E)-3,8-Dimethyl-12-methylidene-13-oxo-4,14-dioxatricyclo[9.3.0.03,5]tetradec-8-en-10-yl] acetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 1 raw suppliers

Chemical Property of [(8E)-3,8-Dimethyl-12-methylidene-13-oxo-4,14-dioxatricyclo[9.3.0.03,5]tetradec-8-en-10-yl] acetate

Chemical Property:

Vapor Pressure:2.76E-08mmHg at 25°C
Boiling Point:449.9°C at 760 mmHg
Flash Point:198.8°C
Density:1.19g/cm³
XLogP3:1.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:2
Exact Mass:306.14672380
Heavy Atom Count:22
Complexity:563

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC(C2C(CC3(C(O3)CC1)C)OC(=O)C2=C)OC(=O)C
Isomeric SMILES:C/C/1=C\C(C2C(CC3(C(O3)CC1)C)OC(=O)C2=C)OC(=O)C

Technology Process of [(8E)-3,8-Dimethyl-12-methylidene-13-oxo-4,14-dioxatricyclo[9.3.0.03,5]tetradec-8-en-10-yl] acetate

There total 5 articles about [(8E)-3,8-Dimethyl-12-methylidene-13-oxo-4,14-dioxatricyclo[9.3.0.03,5]tetradec-8-en-10-yl] acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 35001-24-2
desacetyl laurenebiolide

: 108-24-7
acetic anhydride

: 28272-18-6
pyrethrosin

: Acetic acid (E)-(1S,3S,5S,10R,11R)-3,8-dimethyl-12-methylene-13-oxo-4,14-dioxa-tricyclo[9.3.0.0^3,5]tetradec-8-en-10-yl ester

: C₁₇H₂₂O₆

: C₁₇H₂₂O₆

Guidance literature:: With sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; Yield given. Multistep reaction. Further byproducts given. Yields of byproduct given; 1.) 1 h, 70 degC; 2.) CH₂Cl₂;
DOI:10.1016/0031-9422(83)80100-9

Reference yield:

: 35001-24-2
desacetyl laurenebiolide

: 108-24-7
acetic anhydride

: 28272-18-6
pyrethrosin

: Acetic acid (E)-(1S,3S,5S,10R,11R)-3,8-dimethyl-12-methylene-13-oxo-4,14-dioxa-tricyclo[9.3.0.0^3,5]tetradec-8-en-10-yl ester

: C₁₇H₂₂O₆

: C₁₇H₂₂O₆

Guidance literature:: With sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; Yield given. Multistep reaction. Further byproducts given. Yields of byproduct given; 1.) 1 h, 70 degC; 2.) CH₂Cl₂;
DOI:10.1016/0031-9422(83)80100-9

Reference yield:

: 35001-24-2
desacetyl laurenebiolide

: 108-24-7
acetic anhydride

: 28272-18-6
pyrethrosin

: Acetic acid (E)-(1S,3S,5S,10R,11R)-3,8-dimethyl-12-methylene-13-oxo-4,14-dioxa-tricyclo[9.3.0.0^3,5]tetradec-8-en-10-yl ester

: C₁₇H₂₂O₆

: C₁₇H₂₂O₆

Guidance literature:: With sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; Yield given. Multistep reaction. Further byproducts given. Yields of byproduct given; 1.) 1 h, 70 degC; 2.) CH₂Cl₂;
DOI:10.1016/0031-9422(83)80100-9