N-(cyclohexa-1,4-dienylmethyl)-4-methyl-N-(prop-2-ynyl)benzenesulfonamide

Base Information

• Chemical Name: N-(cyclohexa-1,4-dienylmethyl)-4-methyl-N-(prop-2-ynyl)benzenesulfonamide
• CAS No.: 916916-84-2
• Molecular Formula: C₁₇H₁₉NO₂S
• Molecular Weight: 301.409
• Mol file: 916916-84-2.mol

Synonyms:N-(cyclohexa-1,4-dienylmethyl)-4-methyl-N-(prop-2-ynyl)benzenesulfonamide

Chemical Property of N-(cyclohexa-1,4-dienylmethyl)-4-methyl-N-(prop-2-ynyl)benzenesulfonamide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-(cyclohexa-1,4-dienylmethyl)-4-methyl-N-(prop-2-ynyl)benzenesulfonamide

There total 1 articles about N-(cyclohexa-1,4-dienylmethyl)-4-methyl-N-(prop-2-ynyl)benzenesulfonamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

N-(cyclohexa-1,4-dienylmethyl)-4-methylbenzenesulfonamide (13698-06-1) + propargyl alcohol (107-19-7) → N-(cyclohexa-1,4-dienylmethyl)-4-methyl-N-(prop-2-ynyl)benzenesulfonamide (916916-84-2)

Guidance literature:

With di-isopropyl azodicarboxylate; triphenylphosphine; In tetrahydrofuran;

DOI:10.1002/anie.200702028

Reference yield: 75.0%

N-(cyclohexa-1,4-dienylmethyl)-4-methyl-N-(prop-2-ynyl)benzenesulfonamide (916916-84-2) → (4Z,7Z)-2-tosyl-2,3,6.9-tetrahydro-1H-cycloocta[c]pyrrole

Guidance literature:

With gallium(III) trichloride; In toluene; at 60 ℃; for 0.5h;

DOI:10.1021/ol061801v

Reference yield:

N-(cyclohexa-1,4-dienylmethyl)-4-methyl-N-(prop-2-ynyl)benzenesulfonamide (916916-84-2) → C17H19NO2S + C17H19NO2S

Guidance literature:

With silver tetrafluoroborate; Au(N,N-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)Cl; In toluene; at 10 - 15 ℃; for 0.166667h; Further Variations:; Catalysts; Reagents; Solvents; Temperatures; Product distribution;

DOI:10.1002/anie.200702028

upstream raw materials:

N-(cyclohexa-1,4-dienylmethyl)-4-methylbenzenesulfonamide

propargyl alcohol