ethyl 6-O-tert-butyldiphenylsilyl-4-O-methoxycarbonyl-2,3-dideoxy-α-D-threo-hex-2-enopyranoside

Base Information

Chemical Name:ethyl 6-O-tert-butyldiphenylsilyl-4-O-methoxycarbonyl-2,3-dideoxy-α-D-threo-hex-2-enopyranoside
CAS No.:162934-22-7
Molecular Formula:C₂₆H₃₄O₆Si
Molecular Weight:470.638
Hs Code.:

Synonyms:ethyl 6-O-tert-butyldiphenylsilyl-4-O-methoxycarbonyl-2,3-dideoxy-α-D-threo-hex-2-enopyranoside

Suppliers and Price of ethyl 6-O-tert-butyldiphenylsilyl-4-O-methoxycarbonyl-2,3-dideoxy-α-D-threo-hex-2-enopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of ethyl 6-O-tert-butyldiphenylsilyl-4-O-methoxycarbonyl-2,3-dideoxy-α-D-threo-hex-2-enopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of ethyl 6-O-tert-butyldiphenylsilyl-4-O-methoxycarbonyl-2,3-dideoxy-α-D-threo-hex-2-enopyranoside

There total 5 articles about ethyl 6-O-tert-butyldiphenylsilyl-4-O-methoxycarbonyl-2,3-dideoxy-α-D-threo-hex-2-enopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 79-22-1
methyl chloroformate

: 186598-91-4
(2R,3R,6S)-2-(tert-Butyl-diphenyl-silanyloxymethyl)-6-ethoxy-3,6-dihydro-2H-pyran-3-ol

: 162934-22-7
ethyl 6-O-tert-butyldiphenylsilyl-4-O-methoxycarbonyl-2,3-dideoxy-α-D-threo-hex-2-enopyranoside

Guidance literature:: With pyridine; dmap; In dichloromethane; for 24h; Ambient temperature;
DOI:10.1080/07328309708006546

Reference yield:

: 23339-15-3
ethyl 2,3-dideoxy-α-D-erythro-hex-2-enopyranoside

: 162934-22-7
ethyl 6-O-tert-butyldiphenylsilyl-4-O-methoxycarbonyl-2,3-dideoxy-α-D-threo-hex-2-enopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: 72 percent / Et₃N / CH₂Cl₂ / 24 h / Ambient temperature

2: Ph₃P, DEAD / toluene / 24 h

3: NaOMe / methanol / 12 h

4: 96 percent / DMAP, Py / CH₂Cl₂ / 24 h / Ambient temperature

With pyridine; dmap; sodium methylate; triethylamine; triphenylphosphine; diethylazodicarboxylate; In methanol; dichloromethane; toluene;
DOI:10.1080/07328309708006546

Reference yield:

: [(2R,6S)-2-(tert-Butyl-diphenyl-silanyloxymethyl)-6-ethoxy-3,6-dihydro-2H-pyran-3-yloxy]-acetic acid

: 162934-22-7
ethyl 6-O-tert-butyldiphenylsilyl-4-O-methoxycarbonyl-2,3-dideoxy-α-D-threo-hex-2-enopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: NaOMe / methanol / 12 h

2: 96 percent / DMAP, Py / CH₂Cl₂ / 24 h / Ambient temperature

With pyridine; dmap; sodium methylate; In methanol; dichloromethane;
DOI:10.1080/07328309708006546