6-azido-2,3,4-tri-O-benzyl-6-deoxy-α-D-mannopyranose-1-O-trichloroacetimidate

Base Information

Chemical Name:6-azido-2,3,4-tri-O-benzyl-6-deoxy-α-D-mannopyranose-1-O-trichloroacetimidate
CAS No.:1473360-15-4
Molecular Formula:C₂₉H₂₉Cl₃N₄O₅
Molecular Weight:619.932
Hs Code.:

Synonyms:6-azido-2,3,4-tri-O-benzyl-6-deoxy-α-D-mannopyranose-1-O-trichloroacetimidate

Suppliers and Price of 6-azido-2,3,4-tri-O-benzyl-6-deoxy-α-D-mannopyranose-1-O-trichloroacetimidate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 6-azido-2,3,4-tri-O-benzyl-6-deoxy-α-D-mannopyranose-1-O-trichloroacetimidate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 6-azido-2,3,4-tri-O-benzyl-6-deoxy-α-D-mannopyranose-1-O-trichloroacetimidate

There total 6 articles about 6-azido-2,3,4-tri-O-benzyl-6-deoxy-α-D-mannopyranose-1-O-trichloroacetimidate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 545-06-2
trichloroacetonitrile

: 6-azido-2,3,4-tri-O-benzyl-6-deoxy-α-D-mannopyranoside

: 1473360-15-4
6-azido-2,3,4-tri-O-benzyl-6-deoxy-α-D-mannopyranose-1-O-trichloroacetimidate

Guidance literature:: With 1,8-diazabicyclo[5.4.0]undec-7-ene; In dichloromethane; at 0 ℃; for 0.666667h;
DOI:10.1016/j.carres.2013.08.010

Reference yield:

: 210170-40-4
1,2,3,4-tetra-O-acetyl-6-azido-6-deoxy-α-D-mannopyranoside

: 1473360-15-4
6-azido-2,3,4-tri-O-benzyl-6-deoxy-α-D-mannopyranose-1-O-trichloroacetimidate

Guidance literature:: Multi-step reaction with 5 steps

1: boron trifluoride diethyl etherate / dichloromethane / 12 h / 20 °C

2: methanol; sodium methylate / 0.5 h / pH 9

3: sodium hydride / N,N-dimethyl-formamide / 2 h / 0 °C

4: water; N-Bromosuccinimide / acetone / 1 h

5: 1,8-diazabicyclo[5.4.0]undec-7-ene / dichloromethane / 0.67 h / 0 °C

With methanol; N-Bromosuccinimide; boron trifluoride diethyl etherate; water; sodium methylate; sodium hydride; 1,8-diazabicyclo[5.4.0]undec-7-ene; In dichloromethane; N,N-dimethyl-formamide; acetone;
DOI:10.1016/j.carres.2013.08.010

Reference yield:

: p-tolyl 6-azido-2,3,4-tri-O-benzyl-6-deoxy-1-thio-α-D-mannopyranoside

: 1473360-15-4
6-azido-2,3,4-tri-O-benzyl-6-deoxy-α-D-mannopyranose-1-O-trichloroacetimidate

Guidance literature:: Multi-step reaction with 2 steps

1: water; N-Bromosuccinimide / acetone / 1 h

2: 1,8-diazabicyclo[5.4.0]undec-7-ene / dichloromethane / 0.67 h / 0 °C

With N-Bromosuccinimide; water; 1,8-diazabicyclo[5.4.0]undec-7-ene; In dichloromethane; acetone;
DOI:10.1016/j.carres.2013.08.010