(-)-cis-3-(2'-oxopropyl)-2,2-dimethylcyclopropane-1-carboxylate methyl ester

Base Information

Chemical Name:(-)-cis-3-(2'-oxopropyl)-2,2-dimethylcyclopropane-1-carboxylate methyl ester
CAS No.:14087-75-3
Molecular Formula:C₁₀H₁₆O₃
Molecular Weight:184.235
Hs Code.:

Synonyms:(-)-cis-3-(2'-oxopropyl)-2,2-dimethylcyclopropane-1-carboxylate methyl ester

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Chemical Property of (-)-cis-3-(2'-oxopropyl)-2,2-dimethylcyclopropane-1-carboxylate methyl ester

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Technology Process of (-)-cis-3-(2'-oxopropyl)-2,2-dimethylcyclopropane-1-carboxylate methyl ester

There total 1 articles about (-)-cis-3-(2'-oxopropyl)-2,2-dimethylcyclopropane-1-carboxylate methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 186581-53-3,908094-01-9,334-88-3
diazomethane

: 498-15-7,19079-29-9
(+)-Δ³-carene

: 54878-01-2
2,2-dimethyl-3-(2-oxopropyl)-cis-cyclopropane-1-acetic acid methyl ester

: 14087-75-3
(-)-cis-3-(2'-oxopropyl)-2,2-dimethylcyclopropane-1-carboxylate methyl ester

: 36482-69-6
(1R,4S,6S)-4-hydroxy-4,7,7-trimethylbicyclo[4.1.0]heptan-3-one

Guidance literature:: With potassium permanganate; tetrabutylammomium bromide; Multistep reaction; 1.) aq. acetic acid, 22 deg C, 1 h, 2.) ether;
DOI:10.1007/BF00630245

Reference yield:

: 14087-75-3
(-)-cis-3-(2'-oxopropyl)-2,2-dimethylcyclopropane-1-carboxylate methyl ester

: 121772-11-0,121842-92-0
(1R,3R)-3-((Z)-2-Chloro-3-oxo-propenyl)-2,2-dimethyl-cyclopropanecarboxylic acid 3-phenoxy-benzyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: PCl₅ / 18 h / Ambient temperature

2: SeO₂ / toluene / 24 h / Heating

3: 1.) NaOH, 2.) K₂CO₃ / 1.) MeOH(aq), room temperature, 2.) methylisobutylketone, reflux

4: 82.4 percent / Jones chromic acid

With sodium hydroxide; selenium(IV) oxide; phosphorus pentachloride; chromic acid; potassium carbonate; In toluene;

Reference yield:

: 14087-75-3
(-)-cis-3-(2'-oxopropyl)-2,2-dimethylcyclopropane-1-carboxylate methyl ester

: 121772-10-9,121842-91-9
(1R,3R)-3-((Z)-2-Chloro-3-hydroxy-propenyl)-2,2-dimethyl-cyclopropanecarboxylic acid 3-phenoxy-benzyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: PCl₅ / 18 h / Ambient temperature

2: SeO₂ / toluene / 24 h / Heating

3: 1.) NaOH, 2.) K₂CO₃ / 1.) MeOH(aq), room temperature, 2.) methylisobutylketone, reflux

With sodium hydroxide; selenium(IV) oxide; phosphorus pentachloride; potassium carbonate; In toluene;