aniline dithiocarbamate^(1-)

Base Information

• Chemical Name: aniline dithiocarbamate^(1-)
• CAS No.: 22296-13-5
• Molecular Formula: C₇H₆NS₂
• Molecular Weight: 168.263
• Mol file: 22296-13-5.mol

Synonyms:aniline dithiocarbamate^(1-)

Chemical Property of aniline dithiocarbamate^(1-)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of aniline dithiocarbamate^(1-)

There total 1 articles about aniline dithiocarbamate^(1-) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

carbon disulfide (75-15-0,12122-00-8) + aniline (62-53-3) → aniline dithiocarbamate(1-) (22296-13-5)

Guidance literature:

With 1,4-diaza-bicyclo[2.2.2]octane; In tetrahydrofuran; at 20 ℃; for 24h;

DOI:10.1016/j.cclet.2017.10.015

Reference yield: 98.0%

aniline dithiocarbamate(1-) (22296-13-5) → phenyl isothiocyanate (103-72-0)

Guidance literature:

With iron(III) chloride; sodium acetate; In acetone; at 20 ℃; for 2h; Reagent/catalyst; Solvent; Catalytic behavior;

DOI:10.1080/10426507.2020.1716755

Reference yield: 60.0%

2Pt(4+)*6CH3(1-)*SO4(2-)*4H2O=(Pt(CH3)3)2SO4*4H2O + aniline dithiocarbamate(1-) (22296-13-5) → (Pt(CH3)3S2CNH(C6H5))2

Guidance literature:

In water; aq. soln. ligand was added to stirred aq. soln. trimethylplatinum(IV) sulfate; ppt. was filtered, dried in air, and crystd. at room temp. from benzene- light petroleum; elem. anal.;

DOI:10.1039/b000264j

upstream raw materials:

carbon disulfide

aniline

Downstream raw materials:

bis-(N-phenyldithiocarbamate)palladium(II)

[platinum(IV)(aniline dithiocarbamate)2Cl₂]

phenyl isothiocyanate

Refernces

• 1、 Pendem, Venkata Bhavanarushi,Nannapaneni, Madhavi. "Iron-promoted one-pot approach: Synthesis of isothiocyanates". . p. 485 - 490. Retrieved 2020/02/18.