Methyl 4-[(hydroxyimino)methyl]benzoate

Base Information

Chemical Name:Methyl 4-[(hydroxyimino)methyl]benzoate
CAS No.:168699-41-0
Molecular Formula:C₉H₉NO₃
Molecular Weight:179.175
Hs Code.:
European Community (EC) Number:818-985-8

Synonyms:methyl 4-[(hydroxyimino)methyl]benzoate;168699-41-0;methyl 4-[(E)-hydroxyiminomethyl]benzoate;methyl 4-((hydroxyimino)methyl)benzoate;4-(Hydroxyimino-methyl)-benzoic acid methyl ester;53148-13-3;HMS1757M05;MFCD02060971;AKOS001072933;methyl4-[(hydroxyimino)methyl]benzoate;NCGC00327985-01;BS-43072;Methyl4-[(E)-hydroxyiminomethyl]benzoate;CS-0309864;CS-0370845;EN300-05969;methyl 4-[(1E)-(hydroxyimino)methyl]benzoate;AB01323019-02;Z49568623

Suppliers and Price of Methyl 4-[(hydroxyimino)methyl]benzoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of Methyl 4-[(hydroxyimino)methyl]benzoate

Chemical Property:

XLogP3:2
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:3
Exact Mass:179.058243149
Heavy Atom Count:13
Complexity:195

Purity/Quality:: 97% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)C1=CC=C(C=C1)C=NO
Isomeric SMILES:COC(=O)C1=CC=C(C=C1)/C=N/O

Technology Process of Methyl 4-[(hydroxyimino)methyl]benzoate

There total 4 articles about Methyl 4-[(hydroxyimino)methyl]benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 1571-08-0
methyl 4-formylbenzoate

: 168699-41-0
methyl 4-[(1E)-(hydroxyimino)methyl]benzoate

Guidance literature:: With hydroxylamine hydrochloride; sodium acetate; In methanol; water; Reflux;
DOI:10.1016/j.tetlet.2010.12.090

Reference yield:

: 1571-08-0
methyl 4-formylbenzoate

: 168699-41-0
methyl 4-[(1E)-(hydroxyimino)methyl]benzoate

Guidance literature:

Reference yield:

: 874-60-2
4-methyl-benzoyl chloride

: 168699-41-0
methyl 4-[(1E)-(hydroxyimino)methyl]benzoate

Guidance literature:: Multi-step reaction with 3 steps

1: dmap; triethylamine / dichloromethane / 20 °C

2: 2,4,6-triphenylpyrylium tetrafluoroborate; oxygen / acetonitrile / 16 h / 40 °C / 750.08 Torr / Molecular sieve; Irradiation

3: sodium hydrogencarbonate; hydroxylamine hydrochloride / water; methanol / 0 - 20 °C

With dmap; hydroxylamine hydrochloride; 2,4,6-triphenylpyrylium tetrafluoroborate; oxygen; sodium hydrogencarbonate; triethylamine; In methanol; dichloromethane; water; acetonitrile;
DOI:10.1002/anie.202011815