ethyl 2-(4-O-benzyl-2,3,6-trideoxy-α-L-erythro-hex-2-enopyranosyl)-2(R,S)-nitroacetate

Base Information

• Chemical Name: ethyl 2-(4-O-benzyl-2,3,6-trideoxy-α-L-erythro-hex-2-enopyranosyl)-2(R,S)-nitroacetate
• CAS No.: 361448-59-1
• Molecular Formula: C₁₇H₂₁NO₆
• Molecular Weight: 335.357
• Mol file: 361448-59-1.mol

Synonyms:ethyl 2-(4-O-benzyl-2,3,6-trideoxy-α-L-erythro-hex-2-enopyranosyl)-2(R,S)-nitroacetate

Chemical Property of ethyl 2-(4-O-benzyl-2,3,6-trideoxy-α-L-erythro-hex-2-enopyranosyl)-2(R,S)-nitroacetate

Chemical Property:

Purity/Quality:

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MSDS Files:

Useful:

Technology Process of ethyl 2-(4-O-benzyl-2,3,6-trideoxy-α-L-erythro-hex-2-enopyranosyl)-2(R,S)-nitroacetate

There total 1 articles about ethyl 2-(4-O-benzyl-2,3,6-trideoxy-α-L-erythro-hex-2-enopyranosyl)-2(R,S)-nitroacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

nitroacetic acid ethyl ester (626-35-7) + p-tert-butylphenyl 4-O-benzyl-6-deoxy-2,3-dideoxy-α-L-erythro-hex-2-enopyranoside → ethyl 2-(4-O-benzyl-2,3,6-trideoxy-α-L-erythro-hex-2-enopyranosyl)-2(R,S)-nitroacetate (361448-59-1)

Guidance literature:

With 1,4-di(diphenylphosphino)-butane; tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; In tetrahydrofuran; at 70 ℃;

DOI:10.1081/CAR-100103957

Reference yield: 30.0%

ethyl 2-(4-O-benzyl-2,3,6-trideoxy-α-L-erythro-hex-2-enopyranosyl)-2(R,S)-nitroacetate (361448-59-1) → ethyl 2(R,S)-amino-(4-O-benzyl-2,3,6-trideoxy-α-L-erythro-hexopyranosyl)acetate

Guidance literature:

With hydrogen; palladium on activated charcoal; In ethanol; for 24h; under 760 Torr;

DOI:10.1081/CAR-100103957

upstream raw materials:

nitroacetic acid ethyl ester