(5,10,15,20-tetraphenyl-21-(benzyl)-2-aza-21-carbaporphyrinato)nickel(II)

Base Information

• Chemical Name: (5,10,15,20-tetraphenyl-21-(benzyl)-2-aza-21-carbaporphyrinato)nickel(II)
• CAS No.: 607403-74-7
• Molecular Formula: C₅₁H₃₄N₄Ni
• Molecular Weight: 761.548
• Mol file: 607403-74-7.mol

Synonyms:(5,10,15,20-tetraphenyl-21-(benzyl)-2-aza-21-carbaporphyrinato)nickel(II)

Chemical Property of (5,10,15,20-tetraphenyl-21-(benzyl)-2-aza-21-carbaporphyrinato)nickel(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (5,10,15,20-tetraphenyl-21-(benzyl)-2-aza-21-carbaporphyrinato)nickel(II)

There total 1 articles about (5,10,15,20-tetraphenyl-21-(benzyl)-2-aza-21-carbaporphyrinato)nickel(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

(5,10,15,20-tetraphenyl-2-aza-21-carbaporphyrinato)nickel(II) (177841-46-2) + benzyl chloride (100-44-7) → (5,10,15,20-tetraphenyl-21-(benzyl)-2-aza-21-carbaporphyrinato)nickel(II) (607403-74-7)

Guidance literature:

With potassium carbonate; In dichloromethane; under N2; mixt. of Ni complex and benzyl chloride (6.4 equiv.) in CH2Cl2contg. dibenzo-(18)-crown-6 and suspn. of K2CO3 refluxed for 12 h; solvent evapd. under reduced pressure; dissolved in CH2Cl2; chromd. (silica gel, CH2Cl2); second brown-reddish band collected; crystd. from CH2Cl2-hexane;

DOI:10.1021/ic034096k

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + (5,10,15,20-tetraphenyl-21-(benzyl)-2-aza-21-carbaporphyrinato)nickel(II) (607403-74-7) → (5,10,15,20-tetraphenyl-2-aza-21-carbaporphyrinato)nickel(II) (177841-46-2)

Guidance literature:

With air; In N,N-dimethyl-formamide; Ni complex refluxed for 2 h in DMF with admixture of dry gasoeus HCl; not isolated;

DOI:10.1021/ic034096k

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + (5,10,15,20-tetraphenyl-21-(benzyl)-2-aza-21-carbaporphyrinato)nickel(II) (607403-74-7) → NiCl(N4C20H8(CH2C6H5)(C6H5)4) (607403-76-9)

Guidance literature:

In chloroform-d1; under N2; in NMR tube; HCl added to soln. of Ni complex in CDCl3; not isolated; detd. by (1)H NMR spectroscopy;

DOI:10.1021/ic034096k

upstream raw materials:

(5,10,15,20-tetraphenyl-2-aza-21-carbaporphyrinato)nickel(II)

benzyl chloride

Downstream raw materials:

(5,10,15,20-tetraphenyl-2-aza-21-carbaporphyrinato)nickel(II)

NiCl(N₄C₂₀H₈(CH₂C₆H₅)(C₆H₅)4)