<4S-(2E,4R,5S,6R*,7E)>-5,10-Dihydroxy-4,6-dimethoxy-2,8-dimethyl-2,7-decadienoic acid methyl ester

Base Information

Chemical Name:<4S-(2E,4R*,5S*,6R*,7E)>-5,10-Dihydroxy-4,6-dimethoxy-2,8-dimethyl-2,7-decadienoic acid methyl ester
CAS No.:126502-54-3
Molecular Formula:C₁₅H₂₆O₆
Molecular Weight:302.368
Hs Code.:

Synonyms:<4S-(2E,4R*,5S*,6R*,7E)>-5,10-Dihydroxy-4,6-dimethoxy-2,8-dimethyl-2,7-decadienoic acid methyl ester

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Chemical Property of <4S-(2E,4R*,5S*,6R*,7E)>-5,10-Dihydroxy-4,6-dimethoxy-2,8-dimethyl-2,7-decadienoic acid methyl ester

Chemical Property:

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Technology Process of <4S-(2E,4R*,5S*,6R*,7E)>-5,10-Dihydroxy-4,6-dimethoxy-2,8-dimethyl-2,7-decadienoic acid methyl ester

There total 1 articles about <4S-(2E,4R*,5S*,6R*,7E)>-5,10-Dihydroxy-4,6-dimethoxy-2,8-dimethyl-2,7-decadienoic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 118299-09-5
(E)-(2R,3R,4S)-3,8-Dihydroxy-2,4-dimethoxy-6-methyl-oct-5-enal

: 2605-68-7
methyl 2-(triphenylphosphoranylidene)propionate

: 126502-54-3
<4S-(2E,4R*,5S*,6R*,7E)>-5,10-Dihydroxy-4,6-dimethoxy-2,8-dimethyl-2,7-decadienoic acid methyl ester

: 791-28-6
Triphenylphosphine oxide

Guidance literature:: In dichloromethane; for 12h; Title compound not separated from byproducts; 0 deg C to r.t.;
DOI:10.1021/jo00296a041

Reference yield:

: 126502-54-3
<4S-(2E,4R*,5S*,6R*,7E)>-5,10-Dihydroxy-4,6-dimethoxy-2,8-dimethyl-2,7-decadienoic acid methyl ester

: 118299-13-1,118353-49-4
<2R-<2α(γS*,εS*),3β,5β,6α/β>>-6-Hydroxy-ε,3-dimethoxy-γ,5-dimethyltetrahydro-2H-pyran-2-pentanol benzoate

Guidance literature:: Multi-step reaction with 4 steps

1: pyridine / tetrahydrofuran / Ambient temperature

2: 94 percent / H₂ / BF₄ (Evans catalyst) / CH₂Cl₂ / 51714.8 Torr / Ambient temperature

3: 93 percent / TsOH, 4-A molecular sieves / CH₂Cl₂ / Ambient temperature

4: 94 percent / Li(s-Bu)3BH / tetrahydrofuran / -78 °C

With pyridine; 4 A molecular sieve; hydrogen; L-Selectride; toluene-4-sulfonic acid; [(bicyclo[2.2.1]hepta-2,5-diene)(1,4-bis(diphenylphosphino)butane)rhodium(I)] tetrafluoroborate; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo00262a006

Reference yield:

: 126502-54-3
<4S-(2E,4R*,5S*,6R*,7E)>-5,10-Dihydroxy-4,6-dimethoxy-2,8-dimethyl-2,7-decadienoic acid methyl ester

: 118299-12-0
<3R-<3α,5α,6β(1S*,3S*)>>-6-<5-(Benzoyloxy)-1-methoxy-3-methylpentyl>tetrahydro-5-methoxy-3-methyl-2H-pyran-2-one

Guidance literature:: Multi-step reaction with 3 steps

1: pyridine / tetrahydrofuran / Ambient temperature

2: 94 percent / H₂ / BF₄ (Evans catalyst) / CH₂Cl₂ / 51714.8 Torr / Ambient temperature

3: 93 percent / TsOH, 4-A molecular sieves / CH₂Cl₂ / Ambient temperature

With pyridine; 4 A molecular sieve; hydrogen; toluene-4-sulfonic acid; [(bicyclo[2.2.1]hepta-2,5-diene)(1,4-bis(diphenylphosphino)butane)rhodium(I)] tetrafluoroborate; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo00262a006