tert-butyl 1-(((S,Z)-3-(3-(methoxymethoxy)phenyl)-1-(tert-butyldimethylsilyl)allyloxy)carbonyl)pent-4-enylcarbamate

Base Information

Chemical Name:tert-butyl 1-(((S,Z)-3-(3-(methoxymethoxy)phenyl)-1-(tert-butyldimethylsilyl)allyloxy)carbonyl)pent-4-enylcarbamate
CAS No.:1085406-15-0
Molecular Formula:C₂₈H₄₅NO₆Si
Molecular Weight:519.754
Hs Code.:

Synonyms:tert-butyl 1-(((S,Z)-3-(3-(methoxymethoxy)phenyl)-1-(tert-butyldimethylsilyl)allyloxy)carbonyl)pent-4-enylcarbamate

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Chemical Property of tert-butyl 1-(((S,Z)-3-(3-(methoxymethoxy)phenyl)-1-(tert-butyldimethylsilyl)allyloxy)carbonyl)pent-4-enylcarbamate

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Technology Process of tert-butyl 1-(((S,Z)-3-(3-(methoxymethoxy)phenyl)-1-(tert-butyldimethylsilyl)allyloxy)carbonyl)pent-4-enylcarbamate

There total 1 articles about tert-butyl 1-(((S,Z)-3-(3-(methoxymethoxy)phenyl)-1-(tert-butyldimethylsilyl)allyloxy)carbonyl)pent-4-enylcarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 1085406-14-9
C₁₇H₂₈O₃Si

: 214206-61-8
2-tert-butoxycarbonylamino-hex-5-enoic acid

: 1085406-15-0
tert-butyl 1-(((S,Z)-3-(3-(methoxymethoxy)phenyl)-1-(tert-butyldimethylsilyl)allyloxy)carbonyl)pent-4-enylcarbamate

Guidance literature:: With dmap; N-(3-dimethylaminopropyl)-N-ethylcarbodiimide; In dichloromethane; at 20 ℃; for 4h;
DOI:10.1021/ol802179e

Reference yield:

: 186581-53-3,908094-01-9,334-88-3
diazomethane

: 1085406-15-0
tert-butyl 1-(((S,Z)-3-(3-(methoxymethoxy)phenyl)-1-(tert-butyldimethylsilyl)allyloxy)carbonyl)pent-4-enylcarbamate

: 1085406-16-1
tert-butyl (E,3R,4S)-4-(methoxycarbonyl)-3-(3-(methoxymethoxy)phenyl)-1-(tert-butyldimethylsilyl)octa-1,7-din-4-ylcarbamate

: tert-butyl (E)-4-(methoxycarbonyl)-3-(3-(methoxymethoxy)phenyl)-1-(tert-butyldimethylsilyl)octa-1,7-din-4-ylcarbamate

Guidance literature:: tert-butyl 1-(((S,Z)-3-(3-(methoxymethoxy)phenyl)-1-(tert-butyldimethylsilyl)allyloxy)carbonyl)pent-4-enylcarbamate; With zinc(II) chloride; lithium diisopropyl amide; In tetrahydrofuran; diethyl ether; hexane; at -78 - 20 ℃;

With citric acid; In tetrahydrofuran; diethyl ether; hexane; water; pH=2;

diazomethane; In diethyl ether; at 0 ℃; for 1h; optical yield given as %de;
DOI:10.1021/ol802179e

Reference yield:

: 1085406-15-0
tert-butyl 1-(((S,Z)-3-(3-(methoxymethoxy)phenyl)-1-(tert-butyldimethylsilyl)allyloxy)carbonyl)pent-4-enylcarbamate

: C₂₈H₄₅NO₆Si

: C₂₈H₄₅NO₆Si

Guidance literature:: With zinc(II) chloride; lithium diisopropyl amide; In tetrahydrofuran; at -78 - 20 ℃; for 3h; optical yield given as %de; stereoselective reaction;
DOI:10.1016/j.tet.2009.10.051