C₃₆H₄₁NO₅SSi

Base Information

• Chemical Name: C₃₆H₄₁NO₅SSi
• CAS No.: 144127-41-3
• Molecular Formula: C₃₆H₄₁NO₅SSi
• Molecular Weight: 627.877
• Mol file: 144127-41-3.mol

Synonyms:C₃₆H₄₁NO₅SSi

Chemical Property of C₃₆H₄₁NO₅SSi

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₆H₄₁NO₅SSi

There total 6 articles about C₃₆H₄₁NO₅SSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

t-butyldimethylsiyl triflate (69739-34-0) → C36H41NO5SSi (144127-41-3)

Guidance literature:

Multi-step reaction with 2 steps

1: 99 percent / 2,6-lutidine / CH₂Cl₂ / 1 h / -78 - 0 °C

2: 98 percent / NaH / tetrahydrofuran / 0.08 h / 0 °C

With 2,6-dimethylpyridine; sodium hydride; In tetrahydrofuran; dichloromethane;

DOI:10.1021/ja00049a022

Reference yield:

C26H19NO4 (130031-63-9) → C36H41NO5SSi (144127-41-3)

Guidance literature:

Multi-step reaction with 6 steps

1: 92 percent / cesium carbonate, 18-crown-6 / acetonitrile / 10 h / Ambient temperature

2: 0.5 N aq. LiOH / tetrahydrofuran / 0.5 h / 0 °C

3: triphenylphosphine / CH₂Cl₂ / 0.5 h / 0 °C

4: 68 percent / sodium borohydride / CH₂Cl₂; propan-2-ol / 0.5 h / 0 °C

5: 99 percent / 2,6-lutidine / CH₂Cl₂ / 1 h / -78 - 0 °C

6: 98 percent / NaH / tetrahydrofuran / 0.08 h / 0 °C

With 2,6-dimethylpyridine; lithium hydroxide; sodium tetrahydroborate; 18-crown-6 ether; sodium hydride; caesium carbonate; triphenylphosphine; In tetrahydrofuran; dichloromethane; isopropyl alcohol; acetonitrile;

DOI:10.1021/ja00049a022

Reference yield:

C28H23NO5 (132938-56-8) → C36H41NO5SSi (144127-41-3)

Guidance literature:

Multi-step reaction with 2 steps

1: 99 percent / 2,6-lutidine / CH₂Cl₂ / 1 h / -78 - 0 °C

2: 98 percent / NaH / tetrahydrofuran / 0.08 h / 0 °C

With 2,6-dimethylpyridine; sodium hydride; In tetrahydrofuran; dichloromethane;

DOI:10.1021/ja00049a022

upstream raw materials:

t-butyldimethylsiyl triflate

C₂₆H₁₉NO₄

C₂₈H₂₃NO₅

C₃₃H₂₄N₂O₅S

Downstream raw materials:

C₃₀H₂₇NO₇S

C₃₀H₂₇NO₅S