(SP-5-13)-([tetrakis[2-[2-(2-methoxyethoxy)ethoxy]ethyl] 4,4',4'',4'''-[10-(3-[[6-(1H-imidazol-1-yl)hexyl]oxy]-4-methylphenyl)-21H,23H-porphine-1,15-diylbis(benzene-2,1,3-triyldioxy)]tetrakis[butanamido]]^(2-)-N⁽²¹⁾,N⁽²²⁾,N⁽²³⁾,N⁽²⁴⁾, N⁽³⁾)zinc(II)

Base Information

• Chemical Name: (SP-5-13)-([tetrakis[2-[2-(2-methoxyethoxy)ethoxy]ethyl] 4,4',4'',4'''-[10-(3-[[6-(1H-imidazol-1-yl)hexyl]oxy]-4-methylphenyl)-21H,23H-porphine-1,15-diylbis(benzene-2,1,3-triyldioxy)]tetrakis[butanamido]]^(2-)-N⁽²¹⁾,N⁽²²⁾,N⁽²³⁾,N⁽²⁴⁾, N⁽³⁾)zinc(II)
• CAS No.: 331273-60-0
• Molecular Formula: C₉₂H₁₂₄N₁₀O₂₁Zn
• Molecular Weight: 1771.44

Synonyms:(SP-5-13)-([tetrakis[2-[2-(2-methoxyethoxy)ethoxy]ethyl] 4,4',4'',4'''-[10-(3-[[6-(1H-imidazol-1-yl)hexyl]oxy]-4-methylphenyl)-21H,23H-porphine-1,15-diylbis(benzene-2,1,3-triyldioxy)]tetrakis[butanamido]]^(2-)-N⁽²¹⁾,N⁽²²⁾,N⁽²³⁾,N⁽²⁴⁾, N⁽³⁾)zinc(II)

Chemical Property of (SP-5-13)-([tetrakis[2-[2-(2-methoxyethoxy)ethoxy]ethyl] 4,4',4'',4'''-[10-(3-[[6-(1H-imidazol-1-yl)hexyl]oxy]-4-methylphenyl)-21H,23H-porphine-1,15-diylbis(benzene-2,1,3-triyldioxy)]tetrakis[butanamido]]^(2-)-N⁽²¹⁾,N⁽²²⁾,N⁽²³⁾,N⁽²⁴⁾, N⁽³⁾)zinc(II)

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Technology Process of (SP-5-13)-([tetrakis[2-[2-(2-methoxyethoxy)ethoxy]ethyl] 4,4',4'',4'''-[10-(3-[[6-(1H-imidazol-1-yl)hexyl]oxy]-4-methylphenyl)-21H,23H-porphine-1,15-diylbis(benzene-2,1,3-triyldioxy)]tetrakis[butanamido]]^(2-)-N⁽²¹⁾,N⁽²²⁾,N⁽²³⁾,N⁽²⁴⁾, N⁽³⁾)zinc(II)

There total 1 articles about (SP-5-13)-([tetrakis[2-[2-(2-methoxyethoxy)ethoxy]ethyl] 4,4',4'',4'''-[10-(3-[[6-(1H-imidazol-1-yl)hexyl]oxy]-4-methylphenyl)-21H,23H-porphine-1,15-diylbis(benzene-2,1,3-triyldioxy)]tetrakis[butanamido]]^(2-)-N⁽²¹⁾,N⁽²²⁾,N⁽²³⁾,N⁽²⁴⁾, N⁽³⁾)zinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

Zn(HCO2CH2CH2CH2O)4C6H3C6H3C20H9N4(C6H3CH3(O(CH2)6C3H3N2)) (331273-59-7) + 2-[2-(2-methoxyethoxy)ethoxy]ethylamine (74654-07-2,80506-64-5,869718-87-6) → (SP-5-13)-([tetrakis[2-[2-(2-methoxyethoxy)ethoxy]ethyl] 4,4',4'',4'''-[10-(3-[[6-(1H-imidazol-1-yl)hexyl]oxy]-4-methylphenyl)-21H,23H-porphine-1,15-diylbis(benzene-2,1,3-triyldioxy)]tetrakis[butanamido]](2-)-N(21),N(22),N(23),N(24), N(3))zinc(II) (331273-60-0)

Guidance literature:

With Et₃N; HATU; In N,N-dimethyl-formamide; Zn-complex was dissolved in DMF, ligand was added, cooled to 0°C,HATU and Et3N were added, 2 h at 0°C, stirred for 1 d at room te mp. in the dark; solvent was distilled off under vac. at 40°C, residue was taken up in CH2Cl2/MeOH, purified by FC on SiO2 with CH2Cl2/MeOH, concd. in vacuo, dried under vac. overnight, GPC, dried under vac.;

DOI:10.1002/1522-2675(200202)85:2<599::AID-HLCA599>3.0.CO;2-V

Reference yield: 49.0%

(SP-5-13)-([tetrakis[2-[2-(2-methoxyethoxy)ethoxy]ethyl] 4,4',4'',4'''-[10-(3-[[6-(1H-imidazol-1-yl)hexyl]oxy]-4-methylphenyl)-21H,23H-porphine-1,15-diylbis(benzene-2,1,3-triyldioxy)]tetrakis[butanamido]](2-)-N(21),N(22),N(23),N(24), N(3))zinc(II) (331273-60-0) + iron(II) chloride → Fe(OCH2CH2CH2CONH(CH2)6O3CH3)4(C6H3)2C20H9N4(C6H3CH3(O(CH2)6C3H3N2))(1+)*Cl(1-)=C92H124FeN10O21Cl (331273-61-1)

Guidance literature:

With CF₃COOH; 2,6-lutidine; In chloroform; Zn-complex in CHCl3 was reacted with CF3CO2H at 0°C, stirred at room temp. for 5 min, titrated with 2,6-lutidine, washed with H2O, aq. phase was removed, solvent was distilled off under vac., dried under vac. for 2 h, dissolved in THF; 2,6-lutidine was added, refluxed for 15 min, treated with FeCl2, refluxed for 2 h, cooled to room temp., exposed to air for 30 min, filtered, concd. in vacuo, dried under vac., dissolved in CHCl3, HCl in CHCl3, stirred at room temp. for 5 min, evapd.;

DOI:10.1002/1522-2675(200202)85:2<599::AID-HLCA599>3.0.CO;2-V

Reference yield: 49.0%

hydrogenchloride (7647-01-0,15364-23-5) + (SP-5-13)-([tetrakis[2-[2-(2-methoxyethoxy)ethoxy]ethyl] 4,4',4'',4'''-[10-(3-[[6-(1H-imidazol-1-yl)hexyl]oxy]-4-methylphenyl)-21H,23H-porphine-1,15-diylbis(benzene-2,1,3-triyldioxy)]tetrakis[butanamido]](2-)-N(21),N(22),N(23),N(24), N(3))zinc(II) (331273-60-0) + iron(II) chloride → FeClC20N4H9(CH3C6H3OC6H12C3N2H3)[C6H3[OC3H6CONH(C2H4O)3CH3]2]2 (331273-61-1)

Guidance literature:

With 2,6-dimethylpyridine; N,N,N',N'-tetramethyl-1,8-diaminonaphthalene; trifluoroacetic acid; In tetrahydrofuran; demetallation (CF3COOH, CHCl3, 0°C, 5 min); Fe(II) insertion (FeCl2, 2,6-dimethylpyridine, THF, reflux, 2-4 h); autoxidation (HCl, CHCl3,20°C, 5 min), then (1,8-bis(dimethylamino)naphthalene, THF, 20.d egree.C, 15 min); thin layer chromy. (SiO2, CH2Cl2/CH3OH (90/10)), then gel permeation chromy. (Biorad S-X3, CH2Cl2); elem. anal.;

DOI:10.1039/b007611m

upstream raw materials:

Zn(HCO₂CH₂CH₂CH₂O)4C₆H₃C₆H₃C₂₀H₉N₄(C₆H₃CH₃(O(CH₂)6C₃H₃N₂))

2-[2-(2-methoxyethoxy)ethoxy]ethylamine

Downstream raw materials:

FeClC₂₀N₄H₉(CH₃C₆H₃OC₆H₁₂C₃N₂H₃)[C₆H₃[OC₃H₆CONH(C₂H₄O)3CH₃]2]2

Fe(OCH₂CH₂CH₂CONH(CH₂)6O₃CH₃)4(C₆H₃)2C₂₀H₉N₄(C₆H₃CH₃(O(CH₂)6C₃H₃N₂))⁽¹⁺⁾*Cl^(1-)=C₉₂H₁₂₄FeN₁₀O₂₁Cl

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