[Et₄N][Ni(N,N'-bis(2,6-C₆H₃(i-Pr)2)-2,6-pyridinedicarboxamidato)(OH)]

Base Information

Chemical Name:[Et₄N][Ni(N,N'-bis(2,6-C₆H₃(i-Pr)2)-2,6-pyridinedicarboxamidato)(OH)]
CAS No.:1333474-06-8
Molecular Formula:C₈H₂₀N*C₃₁H₃₈N₃NiO₃
Molecular Weight:689.605
Hs Code.:

[Et<sub>4</sub>N][Ni(N,N'-bis(2,6-C<sub>6</sub>H<sub>3</sub>(i-Pr)2)-2,6-pyridinedicarboxamidato)(OH)]

Synonyms:[Et₄N][Ni(N,N'-bis(2,6-C₆H₃(i-Pr)2)-2,6-pyridinedicarboxamidato)(OH)]

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Chemical Property of [Et₄N][Ni(N,N'-bis(2,6-C₆H₃(i-Pr)2)-2,6-pyridinedicarboxamidato)(OH)]

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Technology Process of [Et₄N][Ni(N,N'-bis(2,6-C₆H₃(i-Pr)2)-2,6-pyridinedicarboxamidato)(OH)]

There total 2 articles about [Et₄N][Ni(N,N'-bis(2,6-C₆H₃(i-Pr)2)-2,6-pyridinedicarboxamidato)(OH)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 210155-53-6
N,N’-bis(2,6-di-iso-propylphenyl)pyridine-2,6-dicarboxamide

: nickel(II) triflate

: 77-98-5
tetraethylammonium hydroxide

: 1333474-06-8
[Et₄N][Ni(N,N'-bis(2,6-C₆H₃(i-Pr)2)-2,6-pyridinedicarboxamidato)(OH)]

Guidance literature:: N,N’-bis(2,6-di-iso-propylphenyl)pyridine-2,6-dicarboxamide; nickel(II) triflate; In tetrahydrofuran; at 20 ℃; for 2h;

tetraethylammonium hydroxide; In tetrahydrofuran; methanol; at 20 ℃; for 14h;
DOI:10.1016/j.ica.2014.10.003

Reference yield: 50.0%

: 210155-53-6
N,N’-bis(2,6-di-iso-propylphenyl)pyridine-2,6-dicarboxamide

: nickel(II) triflate

: tetraethylammonium hydroxide

: 1333474-06-8
[Et₄N][Ni(N,N'-bis(2,6-C₆H₃(i-Pr)2)-2,6-pyridinedicarboxamidato)(OH)]

Guidance literature:: In methanol; N,N-dimethyl-formamide; (N2); std. Schlenk technique; mixt. of ligand and Ni compd. in DMF was stirred for 1 h; treated with soln. of Et4NOH in MeOH; stirred for 1 h; soln. of Et4NOH in MeOH was added; stirred for 10 h; filtered through Celite; ether added; dissolved in THF; stored at -20°C overnight; filtered; ether added to filtrate; filtered; washed (EtOAc, ether); dried; elem. anal.;
DOI:10.1021/ic200942u