[(η2-1,2-bis(diphenylphosphino)ethane)(η5-C5Me5)FeC.ident.C-1,4-C6H4C.ident.CC6H5]

Base Information

• Chemical Name: [(η2-1,2-bis(diphenylphosphino)ethane)(η5-C5Me5)FeC.ident.C-1,4-C6H4C.ident.CC6H5]
• CAS No.: 863992-15-8
• Molecular Formula: C₅₂H₄₈FeP₂
• Molecular Weight: 790.748
• Mol file: 863992-15-8.mol

Synonyms:[(η2-1,2-bis(diphenylphosphino)ethane)(η5-C5Me5)FeC.ident.C-1,4-C6H4C.ident.CC6H5]

Chemical Property of [(η2-1,2-bis(diphenylphosphino)ethane)(η5-C5Me5)FeC.ident.C-1,4-C6H4C.ident.CC6H5]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(η2-1,2-bis(diphenylphosphino)ethane)(η5-C5Me5)FeC.ident.C-1,4-C6H4C.ident.CC6H5]

There total 1 articles about [(η2-1,2-bis(diphenylphosphino)ethane)(η5-C5Me5)FeC.ident.C-1,4-C6H4C.ident.CC6H5] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

[((η2-1,2-bis(diphenylphosphino)ethane)(η5-C5Me5)FeC=CH-1,4-C6H4C.ident.CC6H5]PF6 (863992-21-6) → [(η2-1,2-bis(diphenylphosphino)ethane)(η5-C5Me5)FeC.ident.C-1,4-C6H4C.ident.CC6H5] (863992-15-8)

Guidance literature:

With potassium tert-butoxide; In tetrahydrofuran; (inert atm.); stirring iron complex with excess of potassium tert-butoxide in THF for 2 h; evapn., extn. with toluene, evapn., washing with n-pentane, recrystn. (toluene/pentane); elem. anal.;

DOI:10.1021/om050030g

Reference yield:

ferrocenium hexafluorophosphate + [(η2-1,2-bis(diphenylphosphino)ethane)(η5-C5Me5)FeC.ident.C-1,4-C6H4C.ident.CC6H5] (863992-15-8) → [((η2-1,2-bis(diphenylphosphino)ethane)(η5-C5Me5)FeC.ident.C6H4C.ident.CC6H5]PF6

Guidance literature:

In not given; byproducts: ferrocene; (inert atm.); addn. of ferricinium salt to a soln. of iron complex; not isolated, detected by UV, IR, ESR;

DOI:10.1021/om050030g

upstream raw materials:

[((η2-1,2-bis(diphenylphosphino)ethane)(η5-C5Me5)FeC=CH-1,4-C6H4C.ident.CC6H5]PF6